几种苝系衍生物的修饰和性质研究-有机化学专业论文.docxVIP

山东师范大学硕士学位论文 山东师范大学硕士学位论文 素，从而满足其在太阳能电池等领域的要求。并对这种思路的可行性以及目前存 在的缺陷进行了分析和讨论。 关键词：菲二酰亚胺：不对称修饰：电子给一受体：光物理性质 分类号：0625．15 Ⅱ 山东颊范大学硕士学位论文Abstract 山东颊范大学硕士学位论文 Abstract Inspired by intriguing application in molecular electronics，Ught energy conversion, photocatalysis,and artificial photosynthesis，the photoindueed energy and electron transfer in donor-acccptor systems attract extensive attention．As an important class of functional materials，perylene bisimidc derivative possess many advantages of stable 曲mc嘁，oustanding photoelectron properties,high thermal stability and exhibit wide absorption and emission bands in the visible region,which gall be widely used in organic solar cell，organic solid stale photovoltaic device，organic thin-film field-effect transistor and so on．In this paper，a series of symmetric and asymmetric perylene bisimide derivatives have been designed and synthesized．Three chapters Wele included in present thesis． The research of synthesis．propertis and applications of these perylene bisimide derivatives have been reviewed in Chapter 1．The asymmetric synthesis of these compounds is the novel innovation． 1,7-asymmetrically substimted 3,4：9,10-perylenebis(dicarboximide)dyes(2a，2b， and 3)with electron donor 01acceptor groups have been synthesized in good yields under mild conditions in Chapter 2．The compounds WfffC studied in detail wim electrochemistry and steady-state spec乜oscopy ofthese perylene bisimides to show the electron effects of the substitutions．The strong electron donating pyrrolidinyl／p- tert-butylphenoxy and electron withdrawing bromine substitutes led to a serious deviation fTom intrinsic electronic structure ofthe pcrylene bisimide core：．Futhermore， the packing behaviors both in solid state and in solution were investigated with scanning electron microscopy and absorption spectra respectively．These results w啪 in good agreement with the theory cal“撕ons at B3LYP／6-31G*level and made them a valuable addition to the family of robust perylene-base