回收Fenton铁泥制备高效磁性聚合硫酸铁的研究-环境科学与工程专业论文.docxVIP

高效地降低水中浊度、CODc，，最优投加量分别为150mg／L、100mg／L。最 高效地降低水中浊度、CODc，，最优投加量分别为150mg／L、100mg／L。最 优浊度去除率达到98．86％、98．61％，最优CODc，去除率达到67．35％、67．1l％， 去除效果优于商品聚铁。MPFS更是在沉降速度与絮体致密程度上远远优于 PFS与商品聚铁，初始沉降速度提高十倍，絮体稳定时间从20min加快到 4min，大大缩短了混凝工艺处理时间。 关键词：Fenton铁泥资源回收聚合硫酸铁磁性物质造纸废水 万方数据 THE THE PREPARATl0N OF EFFICIENT啪NETIC POLYMERle FERRIC SULFATE W I TH RECYCLED FENTON I舳N SLUDGE In this study,the research object is the iron mud generated from the paper mill wastewater treatment by Mvanced oxidation period of Fenton process．Properties and composition of Fenton iron mud were analysed；recycle the iron by acid leaching process；take the recovered solution for preparation of highly agglutinative polyferric sulfate coagulant；and at the same time，introduce magnetic IlanO particles，explore the characteristics of polyferric sulfate and magnetic polymerization iron sulfate coagulant products；explore the effect of the products in coagulation experiment,the conclusions ale follows： (I)Recycle the iron from Fenton iron mud by acid leaching谢t11 sulfuric acid．The optimum leaching condition is：take 20：1 liquid-solid ratio witll 3mol／L sulfuric acid and dry iron mud，stirring for 50 minutes in 60C water bath．At this time，the leaching rate of iron reached more than 95％，and remaining stably．There is a positive correlation between the recovery rate of iron sludge and sludge solids reduction rate．The acid leaching recovery is an effective method to reduce the total amount of sludge． (2)Using the recovered Fenton iron mud leaching solution to prepare polymeric ferric sulfate pFS)by alkaline method．And mix PFS with magnetic nanoparticlcs，obtain magnetic polymeric ferric sulfate(MPFS)products．The PFS product,the hi曲aggregation state of iron accounted for 23．6％，in which MPFS accounted for 50．3％．In the characteristic functional groups，polymerization crystal structure，surface structure and other indicators，PFS and MPFS have reachod the requirements of the commodity polymeric ferric sulfate．At the same time，it 万方数据 is