稀土钐聚丙烯酰胺发光材料的合成与性能.docVIP

稀土钐聚丙烯酰胺发光材料的合成及性能 邱硕 ，李运涛 ，杜滕 （陕西科技大学 化学化工学院，陕西 西安 710021） 摘要：以钐离子为中心体，利用二苯甲酰基甲烷（DBM）为第一配体，1，10-菲啰啉（phen）为第二配体与氯化钐在乙醇中反应，加入Gd3+对其敏化，合成了具有发光性能的稀土钐三元配合物Sm/Gd(DBM)3phen。将钐三元配合物与丙烯酰胺（AM）进行共聚反应，制备了一种键合型稀土聚丙烯酰胺共聚物（Sm/Gd (DBM)3phen/PAM）。通过元素分析、傅里叶变换红外光谱、紫外光谱、荧光光谱分析、热重分析测定了配合物及共聚物的组成、结构、发光性能及稳定性。结果表明：Sm/Gd (DBM)3phen/PAM的发光性能优于Sm/Gd(DBM)3phen，在紫外光的激发下于559、597、643 nm处发射出Sm3+的4G5／2—6H5／2、4G5／2—6H7／2、4G5／2—6H9／2跃迁的特征荧光。其中，不发光的Gd3+对于发光的Sm3+的荧光强度有很明显的增强作用。 关键词：稀土；配合物；聚丙烯酰胺；发光材料 中文分类号：O614.33 文献标识码：A Synthesis and Properties of Rare Earth Samarium Polyacrylamide Luminescent Materials QIU Shuo, LI Yun-Tao, DU Teng (College of Chemical Engineering, Shaanxi University of Science and Technology, Xian 710021, Shaanxi, China) Abstract: A luminous ternary complex Sm/Gd(DBM)3phen was synthesized by coordination of samarium using dibenzoyl methane (DBM) as the first ligand, 1, 10-phenanthroline (phen) as the second ligand with samarium chloride in ethanol and with Gd3+ as sensitizer. The obtained samarium ternary complex reacted with acrylamide (AM) to produce a bonded rare earth polyacrylamide (PAM) copolymer (Sm/Gd (DBM)3phen/PAM). The composition, structure, fluorescence properties and stability of complex and copolymer were characterized by means of elemental analysis, Fourier transform infrared spectroscopy, UV spectroscopy, fluorescence spectroscopy and thermogravimetric analysis. The research results showed that the luminescence performance of Sm/Gd(DBM)3phen/PAM was better than that of Sm/Gd(DBM)3phen. The emission characteristics of Sm/Gd (DBM)3phen/PAM at 559 nm, 597 nm and 643 nm originated from the transitions between 4G5/2 and 6H5/2, 4G5/2 and 6H7/2, 4G5/2 and 6H9/2. The non-luminescent Gd3+ had a significant enhancement effect on the fluorescence intensity of luminescent Sm3+. Key words: rare earth; complex; polyacrylamide; luminescent materials Foundation item：Natural Science Foundation of Shaanxi Provincial Department of Science and Technology (2015JM2059) 基金项目：陕西省科技厅自