激光、等离子重熔等离子喷涂Ni包WC涂层参数优化与耐蚀性研究-材料学专业论文.docxVIP

摘 摘 要 通过等离子喷涂可以在基体表面制备性能优良的金属陶瓷涂层，但是等离 子喷涂涂层往往呈层状结构且孔隙率较大，而采用重熔后处理工艺可以有效改进 等离子喷涂涂层的微观组织和耐蚀性能。 本文采用激光重熔、等离子重熔工艺对等离子喷涂涂层进行重熔处理，设 计正交试验，得出激光重熔等离子喷涂涂层的最优参数为：功率600W、速度 1．2m·min1、步距1．8 ITlln，影响因素主次关系为：步距功率速度；等离子重熔 等离子喷涂涂层的最优参数为：电流60A、速度25 cm·min一，影响因素主次关系 为：电流速度。 采用扫描电镜、能谱仪、x射线衍射仪、金相显微镜、显微硬度计对重熔 处理前后以及重熔参数优化前后的涂层组织结构成分进行分析。等离子喷涂涂层 物相为：Ni、WC、Few3C、(Fe，Ni)23C6、NiC；；激光重熔后，WC部分分解形 成WC。和w3c相；等离子重熔后产生W3C并有部分WC被氧化，生成W03。 等离子喷涂涂层孔隙率大，有未熔颗粒、夹杂，不同区域的成分偏析大； 激光重熔后孔隙率降低，仍有少量孔隙和微裂纹；等离子重熔后涂层孔隙率最低 为1．5％，厚度也最小，涂层致密，仅有少量细小的缩孔，成分均匀。重熔处理 后，涂层的硬度均有提高，参数优化后等离子重熔涂层的硬度值最高，且波动小。 对等离子喷涂原样、优化重熔试样进行盐雾以及电化学腐蚀性能对比。等 离子喷涂涂层耐盐雾、电化学腐蚀性能较差，优化重熔涂层耐蚀性能有较大提高， 等离子优化重熔涂层耐蚀性能最好。腐蚀破坏源于涂层中的孔隙、裂纹、夹杂以 及层状组织，腐蚀介质沿着由孔隙、微裂纹、夹杂、颗粒周界形成的阳极通道扩 展。可以通过采用等离子重熔后处理提高等离子喷涂涂层的致密度、降低孔隙率、 弱化涂层层状结构、提高涂层的均匀性来提高耐腐蚀性能。 关键词：等离子喷涂，激光重熔，等离子重熔，WC，参数优化，盐雾腐蚀，电 化学腐蚀 AbstractPlasma Abstract Plasma spraying is one of the most commoIlly used thermal spray techniques，by which cermet coatings with good function could be obtained on metal surface． However,some defects，such as lamellar structure and porosity were existed in plasma sprayed coating unavoidably．Tbe post-processing of remelting was applied to eliminate the defects and the microstructure and corrosion resistance of cermet coatings could be improved effectively． In this paper,laser remelting and plasma remelting techniques Wate employed to remelt the plasma sprayed coatings．The orthogonal experiment was designed to get the optimum parameters of remelting process．The optimum parameters of laser remelting were Power 600W：Scanning velocity 1．2m／s and Moving distance 1．8mm． That of plasma remelting were Current 60A，Velocity 25cm／min．The sequence of factors that affected the laser remelting coatings were Scanning velocity，Power and Moving distance，while the sequence for the plasma remelting coatings were Current and Velocity, Microstructures and phage compositions ofthe coatings both before and after the remelting postprocessing,before and after the parameter optimization as well were studie