甲基萘气相催化合成甲基萘醌的研究-化学工艺专业论文.docxVIP

郑 州 郑 州 大 学 硕 士 学 位 论 文 A b s tr a C t 2一m ethy l一l，4 一naP hthoquin one 15 an imP ortant m ate rial to PreP are vltaJ爪in K an d wi d e ly u se d as th e m id d le P ro du et o f fee d stuff， w ith th e im P ro v e m e ni o f the se ie n e e an d te e hn o lo g y，it e an b e u se d to P reP are m o re m e d ie in e that h av e b io lo g ie al ac tiv ity . U sua lly，the Z一m eth yl一l，4一naPhthoquinone 15 PrePare d by liquid一仲 ase oxidation ，but thi s te e hn iq u e h av e m an y d isad v ant ag e s，su e h as th e P ro d uc tio n restri e tio n ，h ig h se a le o f P o llu tio n a n d d if fi e u lt liq u id w a s te d isP o sa l， e te . In th i s a rt ie le ， th e 2一m ethy l一l，4 .n aPhth o qu in on e 15 P reP are d by gas P h ase eata ly sis ox id ation o f 2 一m ethy l naP hthalen e，this P roeess 15 elear an d h av e m an y other ad v an tages，sueh as lo w - e o st ra w m a te r ia l a n d o x id a nt ，s而 P le P r o d u e tio n e n g in e e r in g . T h e a c tiv e in g r e d ie n t o f e a ta ly s t，e a J汀ie r a n d P re P a ra tio n m e t h o d o f t h e e a ta ly st a re d e te r m in e d b y e o m P a re d to t h e o t h e r r e la te d ，a n d V ZO S 15 se le c te d to b e t h e k e y eo m P o ne ni o f the eata ly st，从 5 0 4 15 the eal以ly st P ro m o ter，siliea g e l 15 the ea rrier an d the catalyst 15 ex eeuted by dip 一m olding . T h e e ffe ct o f e XP an d ing o f e aJ汀ier to e a taly st，s ac tivity is em P h as iz ed ，an d the resu h show s th at the act iv ity of eal以ly st w hich PreP are d by exP an ded e别比ier load ing the ac tiv e in gr e d ie ni 15 b ett e r th an th e e ataly st w hie h P reP are d b y un e x P an d e d e a 币 e r lo a d i n g t he a c tiv e in g r e d ie nt . T h e solub ility o f Z 一m ethy l一l，4 一n aPhth oqu in on e in the ethan ol，aceton e an d to lu e n e a re m e a s u r e d ，a n d to lu e n e 15 d e t en n in e d to b e th e m o