活性炭吸附氧化法降低油田废水的COD研究-化学工程(油田化学)专业论文.docxVIP

浙江大学工程硕士学位论文活性炭吸附氧化法降低油田 浙江大学工程硕士学位论文 活性炭吸附氧化法降低油田 废水的COD研究 摘 要 本论文主要针对王家岗油田外排废水，研究了用活性炭降低油田采出水 中COD的方法。王家岗油田采出水具有温度高、矿化度高等特点，经浮选除 油，絮凝沉降处理后，COD值仍达不到二级污水外排标准，而且进一步降低 其COD较为困难。 本论文基于活性炭对工业废水中石油类、羰基、羟基、胺基等影响COD 值的微量有机污染物的吸附富集作用，研究了不同类型的活性炭及加载催化 剂的活性炭对油田废水的深度降解行为，考察了酸度、活性炭的用量、吸附 时间、温度等对吸附行为的影响。利用活性炭的吸附和催化剂的催化作用， 降低有机物分解的活化能，利用曝气后废水中溶解氧氧化将其除去，从而实 现了石油废水中污染物的深度降解、cOD的达标排放的目的。该方法集吸附、 过滤和催化氧化处理废水中有机污染物于一体。 实验证明，粒状活性炭的吸附效果较棒状的要好，载铜活性炭较未载铜 活性炭吸附效果好，载铜活性炭在pH 5．5效果较好；0。C～45。C范围内，吸 附温度对COD衰减率影响不大；1 kg活性炭可处理O．5m3废水，最佳条件下 载铜活性炭吸附处理油田采出水，COD的最大衰减率约为70％。 关键词：废水 COD 活性炭吸附催化氧化 浙江大学工程硕十学位论文Reduction 浙江大学工程硕十学位论文 Reduction of COD Content in Oilfield Produced Water by Actived Carbon Adsorption Oxidation Abstract The reduction of COD content in oilfield produced water has been discussed in this article．、Vith the features of high temperature and hi妫salinity,the COD content in the Wangjiagang produced water can not meet the requirements for second level discharge standards after the ftoatation separation and flocculating setting and the COD content to be further reduced iS very difficult． On the basis of adsorption enrichment of the activated carbOn on the micro organic pollutants like the oil，carbonyl compound，phenol compound，amide， organic acid and ester which affect the COD content and catalyst-carrying actived carbon on the oilfield produced water has been discussed in the article together with the investigation on the factors(pH value，dosage，adsorption time and temperature)affecting me adsorption accomplished．The activation energy of the organic decomposition Can be reduced under the action of the actived carbon adsorption and catalyst catalysis．The organics call be removed by the dissolved oxygen existing after the aeration打eatment in the produced water．After the above treatments the deep degradation of the COD in the produced water has been achieved and the discharge standard requirements met．The method integrates the adsorption，filtration and catalysis—oxidation together in the tre