糠醛废水中的醋酸回收工艺-化学工业与工程-天津大学.PDF

2006 年 3 月 　　 　化 　学 　工 　业 　与 　工 　程 第 23 卷 　第 2 期 　 Mar . 2006 CHEMICAL 　INDUSTRY　AND 　EN GINEERIN G Vol . 23 　　No . 2 ( ) 　　文章编号 :1004 - 9533 2006 02 - 0142 - 05 糠醛废水中的醋酸回收工艺 张晓辉 ,刘家祺 ,贾彦雷 ,陈亚萍 (天津大学化工学院 绿色合成与转化教育部重点实验室 ,天津 300072) 摘要 :使用自制络合萃取剂 ,采用脉冲填料塔通过络合萃取回收糠醛废水中的醋酸 ,萃取效率可达 到 97 %～99 % 。测定了该物系的液液平衡数据 ,试验考察了影响萃取效率的因素 。以醋酸的精制 可利用减压精馏蒸出和共沸精馏脱水来实现 。萃取液中醋酸蒸出率接近 100 % ,脱水效果良好 ,得 到合格的工业级醋酸 。 关键词 :醋酸 ;络合萃取 ;糠醛 ;废水 中图分类号 :X703 　文献标识码 :A Reclaim Process of Acetic Acid in Waste Water of Furf ural Production ZHAN G Xiaohui , L IU Jiaqi , J IA Yanlei , CHEN Yaping ( Key Laboratory for Green Chemical Technology , School of Chemical Engineering and Technology , Tianj in University , Tianj in 300072 , China) Abstract :Complexation extraction was used to treat the acetic acid in waste water of furfural production . The extraction efficiency can arrive at 97 % —99 %. The reclaim process of acetic acid was implemented by using impulse filling extraction column and a certain extraction solvent . The liquidliquid equilibrium data of the system is determined . The experiment investigated a good many factors that can affect the extraction efficiency . The acetic acid is refined by vacuum distillation and azeotropic distillation . The distillate efficiency of acetic acid in liquid extract can nearly reach 100 % ,and the dewatering effect is good . The qualified acetic acid in technical grade can be obtained . Key words :acetic a