间苯二茂铁磺酸配合物的合成及性质研究-无机化学专业论文.docxVIP

郑州大学2007届硕士毕业论文并咪唑)丁烷)和{[Cd(btmbp)2(H20)2(m—FcphS03)2】 郑州大学2007届硕士毕业论文 并咪唑)丁烷)和{[Cd(btmbp)2(H20)2(m—FcphS03)2】 (CH30H)4(H20),o}n (7)(btmbp=l，10一双(1，2,4-三氮唑甲基)联苯)，其中，6为一维聚合物，7为二维聚合 物，他们结构相同的一点是配体间二茂铁基苯磺酸根均没有与中心金属Cd(II)直接 配位，而是以弱作用填充在主链中间。同时我们还考察了它们的电化学性质，由 于体系中弱作用的影响，使得两个配合物的二茂铁基团半波电位El，2向正极方向稍 微有一些移动。 关键词：二茂铁磺酸聚合物晶体结构离子吸附包含化合物电化学 郑州大学2007届硕士毕业论文Abstract 郑州大学2007届硕士毕业论文 Abstract Recently,the design and synthesis of coordination networks with porous slluc=tures continues tO be a widespread growing field，its exploration is driven in part by the search for novel optical and eleetrosensitive materials as well as for new porous sorbents and catalysts．The selective uptake of specific heavy ions from aqueous solutions has also aroused intensive attention．Porous coordination frameworks， containing phosphates groups，sulfonate groups，and carboxylate groups could be served 勰potential candidates in heavy metal ion sorption by the result of their multiple coordination knots and many coordination modes．Meanwhile，ferrocene-based porous materials could also be widely used in the research of optical and electrochemical materials． In this paper,seven single crystals were obtained by the reactions of the 3-ferrocenylbenzenesulfonate∞一FcphS03Na)and corresponding metal ions．Crystal structures of these complexes were conformed by single crystal X-ray diffraction and IR spectra also were used to characterize the chemical composition of these complexes． Additionally,their electrochemical and ion adsorption properties were also investigated． In presence of small organic ligands(4，4’-bpy,1，3一bpp and 1,2一bpe)，treatment of m-FcphS03Na with Cdoq03)2 or Zn(N03)2 could afforded five polymers 1-5．Their chemical formula arc [Cd(m-FcphS03)2(4，4’-bpy)2]n (1)， 【Zn2(m-FcphS03)4(4，4’一bpy)4]。(2)， 【Cd(m—FcphS03)2(bpp)2]n (3)， [Zn(m-FcphS03)2(bpp)2]n(4)， [Cd(m—FcphS03)：Copeh]n6(CH30H)(5)， respectively． Among these，crystal structures of 1,2，5 could be regard