磺化沥青的合成及应用-化学工程专业论文.docxVIP

磺化沥青的合成及应用摘要磺化沥青是一种性能良好的乳化降粘剂和钻井液添加剂，具有防塌、润滑和降低高温高 压滤失量的作用。渣油是原油加工过程中经减压蒸馏后剩余的组份，是一种组成复杂的混合 物，含有大量的胶质、沥青质，可以用于制备磺化沥青。本文根据钻井液用磺化沥青乳液的 特点，以渣油为原料通过实验探索磺化沥青的制备工艺并对其性能进行评价，研究的主要内 容及结果如下：1、本文首先对渣油进行分离并采用色谱分析各组分的含量，结果表明: 渣油中饱和烃含 量为 6.40%，芳香烃为 23.9%，胶质 44.4%，沥青质为 16.8%。饱和烃含量较少；硫元素含量 为 2.88%，氮含量为 0.83%，属于高含硫氮油品。2、选用三氧化硫替代传统的发烟硫酸作为磺化剂，以二氯乙烷作为溶剂，在釜式反应器 中对磺化工艺进行研究，获得了最佳的磺化工艺条件：磺化剂浓度为 10%，磺化温度 30-40℃，反应时间 30-50min，在 40℃条件下老化 30-60 分钟。同时探讨了渣油与蜡油配比、原料 油稀释比例和剂油比对磺化过程的影响，结果表明：渣油：蜡油配比为 3:2；原料油的稀释 比例为 1:4；剂油比需要控制在 4:1-5:1 之间，磺化效率最高。3、对合成的磺化沥青进行了性能测试，考察了磺化沥青乳液浓度、添加量对降滤失率的 影响，同时对磺化沥青的抗盐、抗钙及耐温性能进行分析，结果表明：样品浓度为 3%、加量 为 10%时，具有良好的降滤失作用，降滤失率达到 47%左右，并且具有抗盐抗钙耐温的优良性 能。关键词：磺化沥青、渣油、磺化、三氧化硫、降滤失率Synthesis and Application of sulfonated asphaltAbstractSulfonated asphalt is a highly effective emulsified viscosity reducer and drilling fluid additive, which has the effect of anti sloughing, lubrication and reducing the high temperature and pressure filtration. The residue is the remainder of oil vacuum distillation. It is a complex mixture containing a lot of glial and asphaltene, and can be used for the preparation of sulfonated asphalt. Based on the characteristics of sulfonated asphalt emulsion for drilling fluid, the paper studies the production technology with residue as the raw material by experiments and evaluates its qualities. The object matters and results are as follows:1, the residue is separated and the content of each component is analysed by chromatographic. The results show that: the content of saturation is 6.40%, the aromatics 23.9%, colloid 44.4% and asphaltene 16.8%. The content of saturation is low. The residue belongs to high sulfur nitrogen oil with the sulfur content 2.88% and the nitrogen content 0.83%.2, with sulfur trioxide instead of fuming sulfuric acid as sulfonating agent and 1,2-dichloroethane as solvent, the sulphonate technology is studied in thesis tank reactor. The optimal conditions are as follows: the sulfonatingagent at a concentration of 10%, the sulfonation tem