缓释型聚羧酸减水剂的合成及性能研究-化学工程与技术专业论文.docxVIP

万方数据 万方数据 Abst Abstract Title:RESEARCH ON THE SYNTHESIS AND PERFORMANCE OF THE SLOW-RELEASE POLY CARBOXYLIC ACID WATER REDUCING AGENT Major: Chemical Engineering and Technology Name:Jinnan Zhong Signature: Supervisor:Prof.Baozhong Du Signature: Abstract This paper in view of problem of the poly carboxylic acid water reducing agent existing in the practical application.According to the principle of molecular design,the esterification reaction based on polyethylene glycol(molecular weight400)with maleic anhydride and acrylic acid have been designed,further free radical copolymerization reaction happening with functional monomer in the role of the initiator.The functional groups -COO-、-COOH、 -OCH2CH2- and -SO3H is contained in the molecular structure of the slow-release carboxylic water reducing agent was synthesized. According to the study of the influences in the esterification and polymerization reaction of reactant ratio,temperature and time,the quantity of inhibitor、catalyst、initiator and solvent by single factor experiment and orthogonal experiment.The results show that,the best performance of acrylic slow-release carboxylic acid water reducing agent synthesis processthe is the esterification molar ratio of n(acrylic):n(polyethylene glycol 400)=1.5:1,reacting at 120℃ with 5 hours,the dosage of the inhibitor and catalyst was 0.4% and 3% to the monomer total quality;the polymerization molar ratio of n(middle compound):n(acrylic):n(maleic anhydride): n(methyl allyl sulfonate)=4:1:3:2,reacting at 75℃ with 4.5 hours,the dosage of the initiator and solvent was 16mL and 5mL.The best performance of maleic anhydride slow-release carboxylic acid water reducing agent synthesis processthe is the esterification molar ratio of n(maleic anhydride):n(polyethylene glycol 400)=1.2:1,reacting at 85℃ with 3 hours,the dosage of the catalyst was 2% to the monomer total quality;the polymerization molar ratio of n(middle compound