甲苯萃取-GFAAS法测定高盐食品中微量砷.PDF

第42卷第3期 中国测试 Vol.42 No.3 2016年3月 CHINA MEASUREMENT TEST March，2016 doi院10.11857/j.issn.1674-5124.2016.03.010 甲苯萃取-GFAAS法测定高盐食品中微量砷 秦樊鑫袁 姜 鑫袁 黄先飞袁 吴 迪袁 庞文品袁 吕亚超 （贵州师范大学 贵州省山地环境重点实验室，贵州 贵阳 550001） 摘 要院建立甲苯萃取-石墨炉原子吸收测定高盐食品中砷的方法遥用微波消解样品袁甲苯萃取分离砷袁硝酸镍作基体 改进剂袁钯涂层石墨炉原子吸收法测定高盐食品中微量砷遥 结果表明院用甲苯萃取砷提高了回收率袁很好地消除基体 干扰曰用硝酸镍作基体改进剂袁提高砷的灰化温度和灵敏度袁方法的相对标准偏差臆1.12%渊n=6冤曰回收率达到97.5%耀 104.5%曰检出限为0.038mg/kg遥 该法灵敏尧准确尧可靠袁可用于高盐食品中微量砷的测定遥 关键词院甲苯；石墨炉原子吸收；高盐食品；砷；基体改进剂 文献标志码院A 文章编号院1674-5124渊2016冤03-0041-04 Determination of trace arsenic in the salty food by GFAAS after toluene extraction QIN Fanxin，JIANG Xin，HUANG Xianfei，WU Di，PANG Wenpin，L譈 Yachao （Guizhou Provincial Key Laboratory for Mountainous Environment，Guizhou Normal University， Guiyang 550001，China） Abstract: A method for determination of arsenic in salty food samples by graphite furnace atomic absorption spectrophotometry （GFAAS）after toluene extraction is established. The samples are digested with a microwave system. Arsenic is extracted and separated from these samples with toluene. The Pd-coated GFAAS determins the contents of arsenic in samples with Ni（NO ） 3 2 as a matrix modifier. The results show that the recovery of arsenic has been improved after toluene extraction，the charring temperature enhanced，and the interference of matrix eliminated. The relative standard deviation of this method is equal or less than 1.12%（n=6）. Recoveries ranging from 97.5% to 104.5%are obtained in the spiked samples. The detection limi