电化学法检测混凝土中钢筋腐蚀之研究.DOC

電化學法檢測混凝土中鋼筋腐蝕之研究 Measure of Steel bar Corrosion in Concrete by Electrochemistry Principle Method 研究生：謝吉昌　　Hsieh, Ji-Chang 指導教授：吳志興　　Wu, Chi-Hsing 【摘要】 本研究以電化學原理的非破壞檢測方法，使用Gecor 8腐蝕分析儀檢量測鋼筋混凝土之鋼筋腐蝕電位、腐蝕電流密度及混凝土電阻係數，並使用Proceq CANIN腐蝕分析儀量測腐蝕電位作比較。混凝土為強度210 kg/cm2配比，試驗之變數為鋼筋號數、保護層厚度、氯離子含量及混凝土齡期，文中並探討欲達到穩定量測值所需的澆水時間和澆水量。 試驗結果顯示，混凝土初期因仍含有孔隙水，所需的澆水量較後期要少；Gecor 8量測腐蝕電位達到穩定值所需的澆水時間最多為70秒，CANIN則需110秒。以MANOVA統計分析結果顯示，試驗變數中鋼筋號數及保護層厚度對腐蝕電位、混凝土電阻係數無顯著差異，其餘變數則有顯著差異；保護層厚度對腐蝕電流亦無顯著差異，其餘變數則對腐蝕流密度皆有影響。本文並發展出各氯離子含量試體之腐蝕電位、腐蝕電流密度、混凝土電阻係數分別對混凝土齡期等多項迴歸關係式。 關鍵字：電化學、非破壞檢測、腐蝕電位、腐蝕電流密度、混凝土電阻係數 【Abstract】 The study employed an electrochemical nondestructive test to measure the corrosion potential, and corrosion current density of steel bar and the concrete resistivity in reinforced concrete, where the Gecor 8 was used to compare with the corrosion potential measured by the Proceq CANIN. Variables of the experiment concluded steel bar diameter, cover depth, chloride ion content and concrete age. The required time and volume of pre-wetting water were also discussed for the measurement value went flat. The results showed that, the pre-wetting time required was less in the beginning period than in later period after concrete was cast. Gecor 8 needed not more than 70 seconds to achieve a stable potential value, while CANIN needed not more than 110 seconds. MANOVA statistical analysis showed that, steel bar diameter and cover depth are not significant to corrosion potential and concrete resistivity, and cover depth is not significant to corrosion current density. Finally, several regression equations of corrosion potential, corrosion current density, concrete resistivity respective to concrete age were developed. Keywords：Electrochemical, Nondestructive Tests, Corrosion Potential, Corrosion Current Density, Concrete Resistivity