碳化对海砂砂浆氯离子结合性能的影响Effectofcarbonationonthe.PDF

碳化对海砂砂浆氯离子结合性能的影响 1,2 1 2 刘伟 谢友均 邢锋 (第一作者身份证号码 （1. 中南大学土木工程学院，长沙，410075 2.广东省滨海土木工程耐久性重点实验室，深圳大学，深圳，518060 ） 摘要：碳化对氯离子结合性能的影响会影响混凝土中钢筋的始锈时间和提供更多的氯离子参 与钢筋腐蚀扩展过程，使海砂混凝土结构遭受超过预期的腐蚀破坏风险。采用不同氯离子含 量的海砂砂浆和盐水砂浆，研究了碳化对砂浆氯离子结合能力的影响。试验结果显示，碳化 后海砂砂浆氯离子结合能力只有碳化前的10%，碳化作用下Friedel 盐及(C-S-H)凝胶的分解 分别是影响化学结合及物理吸附氯离子的主要原因。 关键词：碳化; 氯离子; 结合; 海砂 中图号：TU528 文献标示码: A 文章编号： Effect of carbonation on the chloride binding of mortar made with marine sand LIU Wei1,2 XIE You-jun1 XING Feng2 (1. College of Civil Engineering, Central South University, Changsha, 410075; 2. Guangdong Provincial Laboratory of Durability for Marine Civil Engineering, Shenzhen University, Shenzhen, 518060) Abstract: The concrete structure made with marine sand might be subjected to an overwhelming risk of corrosion damage due to the effect of carbonation on the chloride binding, which could advance the initiation time of steel corrosion and provide more available chloride during for corrosion process. Therefore, effects of carbonation on the chloride binding of mortar made with different chloride content were researched in this study. The results show that, the chloride binding ability of carbonated marine sand mortar remain 10% compared to these of uncaonated mortar. The Frield salt and C-S-H gel can be decomposed because of carbonation, which will cause the poor physical and chemical binding capability of concretes on chloride. Key word: Carbonation; chloride; binding; marine sand 与河砂相比，海砂中携带的氯盐是限制其在钢筋混凝土结构中使用的主要原因，若使 [1-3] 用未净淡化处理的海砂有可能导致严重的混凝土质量或钢筋腐蚀等耐久性问题 。目前， 在钢筋混凝土结构中直接使用未经净化处理或净化处理不合格的海砂已经成为我国沿海地 区特有的工程质量问题，如2013 年央视315 专题报道，深圳地区在建工