正丁烷脱氢制正丁烯催化剂3.PDF

第 19 卷 第 10 期 化　学　进　展 Vol. 19 No. 10 2007 年 10 月 PROGRESS IN CHEMISTRY 　Oct. , 2007 正丁烷脱氢制正丁烯催化剂 胥月兵　陆江银 　王吉德 (新疆大学 石油天然气精细化工教育部重点实验室 　乌鲁木齐 830046 ) 摘 　要 　综述了对正丁烷脱氢制备正丁烯的催化剂体系 ,包括有氧脱氢中钒基催化剂、钼酸盐系列和焦 磷酸盐系列催化剂 ;催化脱氢中贵金属 Pt 系催化剂、以 ZSM5 分子筛为载体的催化剂以及膜反应器。探讨 了正丁烷脱氢动力学 ,并在Marsvan Krevlen 和 EleyRideal 机理模型动力学基础上归纳了正丁烷氧化脱氢及 直接脱氢的机理。讨论了正丁烷脱氢催化剂的影响因素 , 比较了各类催化剂的特点并对其进行展望,认为 ZSM5 分子筛将可能成为正丁烷脱氢制正丁烯的新的研究热点。 关键词 　正丁烷 　脱氢 　催化剂 　动力学 　反应机理 ( ) 中图分类号: O64336 ; TQ0314 　文献标识码 : A 　文章编号 : 1005281X 2007 Catalysts for nButane Dehydrogenation to 1Butene Xu Yuebing 　Lu Jiangyin 　Wang Jide ( Key Laboratory of Oil Gas Fine Chemicals , Ministry of Education , Xinjiang University , Urumqi 830046 , China) Abstract 　The series of catalysts for dehydrogention of nbutane to 1butene , including oxidative dehydrogenation with vanadiumbased ,molybdate ,metal pyrophosphate catalysts and catalytic dehydrogenation with Ptbased catalysts and ZSM5 zeolite are reviewed , and the membrane reactor with catalysts is discussed. The kinetics for butane dehydrogenation , the reaction mechanism of nbutane oxydehydrogenation and direct dehydrogenation based on Marsvan Krevlen and EleyRideal kinetics are reviewed. The characteristics of several catalysts are compared and the catalyst ZSM5 zeolite would likely be the reserch hotspot for nbutane dehydrogenation to 1butene. Key words 　nbutane ; dehydrogenation ; catalysts ; kinetics ; reaction mechanism MTBE 。同时正丁烯的需求量将会以64 %的年平均 1 　引言