面向锂负极的隔膜涂层对锂-硫电池性能的影响研究-材料工程专业毕业论文.docxVIP

北京化工大学硕士学位论文在20(hnA／g充放电电流密度下，首次放电比容量提高到1283mAh／g， 北京化工大学硕士学位论文 在20(hnA／g充放电电流密度下，首次放电比容量提高到1283mAh／g， 循环100次后比容量仍有712mAh／g，且锂负极表面形貌保持稳定， 元素硫的附着大大减少。且证明了隔膜该涂层可降低了电池内阻和极 化现象，减少了电解液与锂负极之间的副反应，抑制了枝晶生长。 3、对锂负极保护用有机硅聚二甲基硅氧烷(PD淞)隔膜涂层 的制备及性能进行了探索。实现了在200mA／g充放电电流密度下， 首次放电比容量为1043mAh／g，100次循环后比容量为81 8mAWg， 容量保持率提高到78％，有效地提高了电池的循环稳定性。通过充放 电测试发现，PDMS涂层可减小极化作用，提高电化学活性，阻隔 多硫离子穿梭，抑制锂枝晶生长，进而保护锂负极。这一结果未见文 献报道。 关键词：锂一硫电池，隔膜涂层，锂负极保护，多硫化锂 万方数据 英文摘要THE 英文摘要 THE EFFECT OF SEPARATIoN ANODE COATINGS ON PROPERTIES OF UTHIUM．SULFUR BATTERY ABSTRACT Lithium-sulfur battery has attracted tremendous attention from the energy storage community,mainly due to its high theoretical energy density,which is more than twice that of conventional Li—ion batteries； this makes it one of the most promising candidates to meet the energy needs．However，to use Li metal as an anode is a challenging task because the Li anode forms dendritic and mossy metal deposits，leading to low Coulombic efficiency and short cycle life，as well as safety concerns． Taking into account of these problems，the separator coatings facing lithium anode were designed and prepared creatively for improving the properties of lithium—sulfur battery in the research． 1．The PVDF separator coating facing lithium anode was prepared successfully for improving the properties of lithium-sulfur battery．The results showed that when the thickness of coating layer was only 2．5肌m， the initial discharge specific capacity is 1173mAh／g and the reversible capacities after 80 cycles reach to 722mAh／g．which the average coulombic efficiency increases to 99％at the current of 200I删g．It is demonstrated that PVDF coating is quite effective in reducing shuttle effect and protecting lithium anode corrosion． 万方数据 北京化工大学硕士学位论文2．The 北京化工大学硕士学位论文 2．The LiN03／A1203／PVDF separator coating was designed and prepared firstly to protect the lithium anode and improve the properties of lithium—sulfur battery by the dual role of A120B／PVDF and LiN03 sustained release．A