锰包覆羟基磷灰岩去除高砷酸矿水及Matlab迁移数值模拟-地质工程专业毕业论文.docxVIP

西南科技大学地质工程硕士专业 西南科技大学地质工程硕士专业学位论文 第 PAGE IV 页 西南科技大学 西南科技大学地质工程硕士专业学位论文 第 PAGE III 页 Abstract Arsenic in the acid mine drainage comes from the weathering of arsenic-containing pyrite and arsenopyrite, which leads to the high concentration arsenic of surface and groundwater. It threatens the environment and local people satefy. Permeable reactive barrier (PRB) is a effective treatment technology for acid mine drainage, which remove most of heavy metals and arsenic by adsorption and precipitation. In this study, we took bone char and arsenic (V) respectively as alkali media and contaminant. With building the different loads of manganese coating on media, we experimentally investigated the effects of coating layer on adsorption behaviors, including maximal adsorption, kinetic and desorption. The transport behavior of arsenic (V) in bone char also was investigated using column experiment, the corresponding relation of coating layer and retention ability of arsenic (V) was quantitatively described. At the same time, the Five factors and three levels 27 groups factorial experiment to investigate Fe, Al, Mn three common cation effect on the migration behavior of arsenic. As transport was modeled based on Matlab. The main results of study can summrized as follow: Manganese-coated layer can efficiently improve the adsorption capacity of arsenic (V) on bone char as high as 78 times than fresh bone char. The maximum adsorption capacity is 9.46 mg/g at pH=4 for As (V). Manganese-coated layer immobilize more arsenic (V) than fresh bone char under the same desorption condition. The desorbed arsenic proportion from various manganese-coated bone char is 0.02-0.6% of adsorbed arsenic amount, which is superior to fresh bone char (30%). Two desorption processes were found in those high manganese-coated bone char (B5, B6 and B7). The retention intensity of arsenic (V) in bone char linearly increases with the manganese-coated amount, which the retardation factor (Y) = 15.1 X (m