煤矸石对水中磷的吸附特性研究-环境科学与工程专业毕业论文.docxVIP

摘要 (3)吸附等温线可知煤矸石对磷的最大吸附量为2．26 mg／g,高于高岭土和蒙 脱石等其他天然矿物质对磷的吸附量。煤矸石对磷的吸附过程更符合Langmuir 模型、伪二级动力学方程，说明煤矸石对磷的吸附属于单层吸附、吸附类型为化学吸附。颗粒内扩散方程中三个阶段的拟合效果较好，说明外扩散和颗粒内 扩散模式共同决定了反应速率。由热力学结果可知，吸附反应是自发、吸热、 物理吸附的过程。综合动力学和热力学研究结果，煤矸石吸附磷的反应是物理 吸附和化学吸附共存的过程； (4)在酸性溶液中煤矸石的解析磷效果最好，其次为碱性溶液，在纯水中也 有少量的析出。在一定浓度范围内，酸和碱的浓度越高，解析效果越好。经过 长时间的浸泡，煤矸石的浸出液只检出一种重金属元素Zn，且其含量远低于《地表水环境质量标准》(GB3838．2002)#的III类标准值，说明煤矸石可以作 为吸附剂应用到水体中磷的吸附去除。关键词：磷酸根；煤矸石；吸附性能；吸附机理万方数据ABSTRACTADSORPTl0N CAPACITY OF COAL GANGUE TO PHOSPHATE INABSTRACTEutrophication is a problem which is urgent to be solved in china and the whole world．Phosphate is the decisive factor that cause eutrophication of waterbodies．Therefor，the removal of phosphate is the key to solve the problem in water bodies．Coal gangue is one of large industrial solid wastes in Our country，it does harm to the ecological environment and human health when dumped in theenvironment．In this paper，coal gangue was used as solid adsorbent to remove thephosphate in water,providing reference data to solve the problem of eutrophicationand coal gangue．A variety of analysis methods were used to analyze the character of the adsorption material，revealing the possibility of its adsorption of phosphate．The effects of different particle sizes，the pH of solution，coexisting ions，differentconditions of temperature and concentration were studied．Fitting the experimentaldata by different adsorption isotherm models，adsorption kinetics andthermodynamic formulas to analyze the adsorption process．At the same time，the desorption ability of phosphate and the leaching of heavy metals elements in coal gangue was studied，providing a certain reference value in practical application．The main conclusions are as follows：(1)Kaolinite and quartz were the main composition of coal gangue，the structure of万方数据ABSTRACTthe coal gangue was flaky；BET test results showed that the distribution of pore diameter of coal gangue was uneven，the pore structure mainly consisted of mesoporous，a small amount of micro