氢键识别超分子聚合物的新进展3.pdf

第 19 卷 第 5 期 化　学　进　展 Vol. 19 No. 5 2007 年 5 月 PROGRESS IN CHEMISTRY 　May , 2007 氢键识别超分子聚合物的新进展 王　宇　唐黎明 (清华大学化学工程系高分子研究所 　北京 100084) 摘 　要 　近年来 , 由于氢键作用对聚合物的热力学性质、微观自组装、结晶及液晶行为的重要影响,氢键 识别在超分子聚合物的分子设计与结构控制方面的应用受到广泛关注。本文系统介绍了氢键识别体系的类 型与性质 , 以及分子结构、分子内氢键对氢键识别强度的影响,讨论了羧酸与吡啶间氢键识别体系、与核苷相 关的氢键识别体系以及四重氢键识别体系在超分子聚合物中的最新应用 ,主要介绍了氢键识别超分子聚合 物的合成、结构、性质及功能。 关键词 　氢键 　分子识别 　超分子聚合物 　自组装 ( ) 中图分类号: O631. 3 ; O641. 3 　文献标识码 : A 　文章编号 : 1005281X 2007 Hydrogen Bonding Recognition in Supramolecular Polymers Wang Yu 　Tang Liming ( Institute of Polymer Research , Department of Chemical Engineering , Tsinghua University , Beijing 100084 , China) Abstract 　The application of hydrogen bonding recognition in designing and controlling over supramolecular polymers has attracted great attention recently due to the influence of hydrogen bonds on the thermodynamic properties , microscopic selfassembling , crystallizing and liquid crystallizing behaviors of such polymers. In this paper , the types and characters of hydrogen bonding systems , and the influences of molecular structures and intermolecular hydrogen bonds on the stability of hydrogen bonding systems are described systematically. The recent applications of hydrogen bonding recognition systems , including carboxylic acids and pyridine based system , nucleobase derived system and quadrupolar hydrogen bonding system , in supramolecular polymers are introduced. The synthetic methods , structures , properties and function