河口感潮区表层沉积物.pdf

Advances in Environmental Protection 环境保护前沿, 2014, 4, 166-172 Published Online August 2014 in Hans. /journal/aep /10.12677/aep.2014.44023 The Characteristics of Phosphate Adsorption on Surface Sediments in Estuary 1 2 3,4 1 Shuhui Liu , Jian Zhang , Xilai Zheng , Jian Li 1 Qingdao Entry-Exit Inspection and Quarantine Bureau, Qingdao 2 Qingdao PONY Test, Qingdao 3 Key Laboratory of Marine Environmental Science and Ecology, Ministry of Education, Ocean University of China, Qingdao 4 College of Environmental Science and Engineering, Ocean University of China, Qingdao Email: zjkadan@163.com th st th Received: Jun. 20 , 2014; revised: Jul. 21 , 2014; accepted: Jul. 28 , 2014 Copyright © 2014 by authors and Hans Publishers Inc. This work is licensed under the Creative Commons Attribution International License (CC BY). /licenses/by/4.0/ Abstract The adsorption kinetics and thermodynamics of phosphate onto 3 typical surface sediments from the estuary of Li Cun River and the influencing of temperature and salinity on kinetics were inves- tigated. The adsorption kinetics process can be divided into 3 phase: fast adsorption stage (0 - 1 h), slow adsorption stage (1 - 12 h) and balance stage (12 h). Increased salinity can inhibit phos- phate adsorption and increased temperature promotes the adsorption. The reaction rate of the system speeded up and the balance time advanced when the temperature improved. Adsorption isothermal curve of PO3− -P corresponds with Langmuir isothermal adsorption equation. The