铝基柱撑蒙脱石的制备与表征-材料学专业毕业论文.docxVIP

硕士学位论文ABSTRACT 硕士学位论文 ABSTRACT Al-pillared montmorillonites iS a new catalytic material with large surface area,high thermal stability and surface activity．In this work， montmorillonite ore from Xinyang，Henan provice was been purified and sodium-modified，A113-pillared montmorillonite and A124-pillared montmorillonite was prepared and characterized． Montmorillonite has been beneficiated by sedimentation separation process with sodium hexametaphosphate as dispersant，producing an ultra-pure montmorillonite，which the content of montmorillonite was 93．89％．Then sodium percarbonate was chose as modification agent to produce Na-montmorillonite． A1C13 solution Was hydrolysed by NaOH to gain Alls-pillaring agent． All3-pillared montmoriUonite Was prepared by Na-montnorillonite as stroma and All3 as pillaring agent．The spacing distance d(∞1)value of Na—montmorinollite was 1．2726 nnl，but that of Alls-pillared montmorillonite Was 1．8948 11111．After Alls-pillared montmorillonite being calcined at 500C，its product Was quit stable，which the basal interlayer spacing d(ooD was stabilized at 1．8036 nl／1． 越24-pillared montmorillonite Was prepared using A124-pillaring agent,which Was gained by a method of adding aluminum foil into the A1CIs solution．The formation conditions and properties of pillared interlayer montmorillonite were determined．The experimental results showed that aging time 55h under 97．5℃，the suspending liquid concentration of Na-montmorillonite l％。Al／montmorillonite 10mmol／g and pillared reaction time 48h．A124-pillared montmorillonite with a large basal spacing，d(001)=2．0533 nnl，has been produced．After砧24-pillared mont—morillonite being calcined at 700。C，its product Was quit stable， which the basal interlayer spacing d(001)was stabilized at 1．7873哪． The IR results of montmorillonite being calcined at different temperatures showed that the IR spectra of A124-pillared montmorillonite were almost agreed with Na-montmorillonite．The structure of octahedron sheet of A124-pil