抗静电超高分子量聚乙烯管材生产技术开发研究-材料加工工程专业毕业论文.docxVIP

pU川人学坝t。学位论文抗静电超高分子量聚乙烯管材生产技术并发研究 pU川人学坝t。学位论文 抗静电超高分子量聚乙烯管材生产技术并发研究 材料加工工程专业 研究生：万莉 指导教师：刘廷华教授 摘要：UHMWPE是一种性能卓越的新型工程塑料，因其制备的管材具有优 异的性能，有重要的应用价值和巨大的市场前景。但由于UHMWPE是典型的 绝缘材料，由其制造的管材在使用过程中极易产生静电，因而影响了管材的实 际应用。本文采用了炭黑和膨胀石墨等导电填料对其进行抗静电改性，并探讨 了它们对共混体系的导电性能、力学性能、磨损性能和流动性能的影响。另外， 本文还探讨了螺杆组合对挤出成型的影响，优化并设计制造出了UHMWPE的 管材挤出成型装置，对经过抗静电改性的UHMWPE体系实旌了双螺杆连续挤 出管材的实验研究，并最终获得了抗静电性能良好且机械性能优异的管材制品 的最佳工艺及设备条件。 关键词：UHMWPE；抗静电{炭黑；膨胀石墨；螺杆组合；机头；管材； 挤出成型 抗静电超高分子量聚乙烯管材生产技术开发研究Research 抗静电超高分子量聚乙烯管材生产技术开发研究 Research on Processing Technology of Antistatic UHMWPE Pipe Major：Material Processing Engineering Postgraduate：Wan Li Supervisor：Pmf‘Tinghua Liu ABSTRACT：The ultra high molecular weight polyethylene(UHMWPE)is new type witll engineering plastics of outstanding properties．And the pipes made of UHMWPE have many outstanding properties SO that they have important application value and great market foreground．But the applications of UHMWPE pipe are influenced by its shortages，such as its representative insulation．In this paper,the antistatic modification of UHMWPE is researched by adding carbon black(03)and expanded—graphite∞G)．And the electrical conductivity,mechanical properties， wearing quality and fluidity of conductive fillings filled the composites investigated．Besides，the effect of the screw configuration and combination on pipe extrusion is investigated．Modification，design and fabrication have been carried out on the extrusion equipment．And the effect of the structure of die and the screw element configuration to extrude pipe on the blend of UHMWPE investigated． The result shows that blend by CO—rotating twin-screw extrusion is more effective， and eminent processing and equipment conditions to gain better electrical conductivity and other properties pipes are achieved in this status． Keywords： UHMWPE；antistatic； carbon black(CB)；die；pipe； expanded．graphite(EG)；screw configuration； extrusion 四川太学硕士学位论文1绪论 四川太学硕士学位论文 1绪论 1．1 UHMWPE概述 1 1．1UHMWPE的发展简史 超高分子量聚乙烯通常是指相对分子质量在150力-以上的线型聚乙烯，