麦草不同蒸煮方法中主要化学成份降解的动力学研究-制浆造纸工程专业毕业论文.docxVIP

ABSTRACTStudies ABSTRACT Studies on Kinetics of Main Components Degradation Based Wheat Straw Cooking Process As a kind of fiber material．wheat s订aw plays an important role in China．It is of great important tO study kinetics of delignification and degradation of cellulose and hemicellulose． The application ofthe theory in the process control is promising． This study iS focused on the kinetics of delignification and degradation of cellulose and hemicellulose based on pulping process．It is showed in the result after the analysis of lignin， cellulose and hemicellulose content Fernained in the pulp in difierent time and at various temperature，which means that the deligniftcation and degradation of cellulose and hemiceI!cse 1‘．3 quite easy,especially at hi曲temperatuae．mi 11．1c-temperature is the key elemem that affects the cooking process．The rate constant and the order of reaction are determined through the establishment ofkinetic equation in deligniftcation and degradation ofcellulose and hemicellulose reaction． Kinetic equation in delignification reaction ofAP--AQ： 13’1 一dL／dt=KL(OH一)1 20(AQ)o 12加25，me average active energe E=34212 Cal／m01． Kinetic equation in delignification reaction of KP—AQ： 26’1 ．dL／dt=KL(OH一)1 39(HS一)o 22加24(AQ)。64^0 67，the average active energe E=29270 Cal／m01． Lignin degradation of KP—AQ is faster than AP—AQ．Bot}1 in these processes，lignin degradation have three phases：primary lignin degredation，complement lignin degredation and residue lignin degredation．In the primary phase ofAP—AQ lignin degredate 54％ofthe totle lignin content，in KP—AQ may degredate 60％． Kinetic equation in degradation ofhemicellulose reaction ofAP—AQ： 84~3 ．dChemiceIlul。sddt=K+Chem。cc】1ube(OH一)2 49(AQ)o·24～o”，the average active energe E=4 1 94 Cal／m01． KinetiC equation in degradation ofhemicellulose reaction ofKP—AQ： 174 06～1 13～1 一dChemiceIlul。sddt=K Chemicc㈨。sc(OH一)3 65(SH一)1 39(AQ)1 41，me average active energe E=5210 Cal／m01． Both in AP—AQ and KP—AQ，degredation of pento