黄磷废水中微量碘提取的动力学研究-材料学专业毕业论文.docxVIP

贵州大学硕士学位论文 贵州大学硕士学位论文 II II Study on the dynamic of extracting micro amounts of iodine from Yellow Phosphorus Wastewater ABSTRACT This paper experiments the process of extracting micro amounts of iodine from Yellow Phosphorus Wastewater, Which based on the production technology status of iodine industry system in our country and the actual production situation for iodine recycling process of a company in Guizhou province. This paper firstly experiments the iodine’s oxidation rate under different condition, and systematically studies several factors’ influence on oxidation proceeding, including concentrated sulfuric acid, hydrogen ion, iodide concentration, hydrogen peroxide concentration and temperature. Based on above, we get related date in large quantity. At the same time, this paper also analyses and studies the oxidation dynamic equation and chemical reaction mechanism through experiments’ result and related references. In addition, this paper also studies the reduction-absorption dynamic characteristics, and establish reaction model, analyses the reliability of reaction model through experiments at the same time. The oxidation experiments’ result is as follows: the total oxidation reaction equation is r= k[I? ][H O ] + k [I? ][H O ][H+ ] + k [I? ][SO2? ][H+ ]/(a+[H+ ]), according to 1 2 2 2 2 2 3 4 which rate constants k1 , k2 , k3 correspond to the oxidations of iodide ion 2 2 3 2by H O , H 2 2 3 2 H2 SO5 , respectively. In the absence of sulfate radical ion, the total oxidation reaction can be viewed as ‘first order’. The oxidation reaction is complex due to the presence of concentrated sulfuric acid. The reaction rate is different under different hydrogen ion concentration, and the rate vs. [H+] plots are curve. The result shows that the kinetic order of hydrogen peroxide is zero, and the kinetic order of sulfate radical ion is first. In the analysis of the amount of catalyst, concentrated sulfuric acid, the experiment must contr