洛克沙胂对生物除磷过程的影响研究-市政工程专业毕业论文.docxVIP

I I 洛克沙胂对生物除磷过程影响的研究 摘要 洛克沙胂作为饲料添加剂，广泛应用于畜禽养殖业中，它们在动物体内很少降解， 大部分以原型的形式随动物粪便排出体外，最后进入养殖废水和环境，为生物除磷的 过程带来一定的挑战，并给生态环境带来一定的风险。本论文以含有洛克沙胂的废水 作为研究对象，研究洛克沙胂对废水处理中的微生物和除磷过程的影响，剖析洛克沙 胂对生物除磷机理的干预，并研究洛克沙胂在生物除磷过程中的生物转化。主要结论 如下：（1）短期试验表明，洛克沙胂对生物除磷过程有抑制作用，尤其对积磷阶段的 抑制更为明显，当洛克沙胂的浓度大于 80 mg L-1 时，生物除磷系统除磷能力基本丧 失；通过抑制模型对释磷速率和积磷速率进行分析，发现当洛克沙胂浓度小于 40 mg L-1 时，洛克沙胂对释磷速率的抑制作用较大，当浓度大于 40 mg L-1 时，对积磷速率 抑制作用较大。（2）长期实验表明，洛克沙胂对生物除磷的过程有一定的抑制作用， 使得污泥颗粒粒径、沉降速率、密实度、灰度和复杂度的增大，但是对原生动物形态 的影响较小。（3）洛克沙胂在生物除磷过程中会发一系列生物降解转化，系统中监测 到 3-氨基-4-羟基苯砷酸（HAPA）和无机砷的出现；静态实验结果表明，洛克沙胂在 0-6 h 内没有进行生物降解转化，其降解模型符合一阶动力学模型，降解产物 HAPA 的生成和降解模型分别符合线性和一阶动力学模型。 关键字：洛克沙胂 生物除磷 降解 抑制 II II Performance of biological phosphorus removal system in presence of roxarsone ABSTRACT Roxarsone have been widely used in chicken and swine feeding as additive, which do not degrade in animal body, and would be present in animal wastewater, challenging the biological phosphorus removal processes. In this study, we investigate the performance of biological phosphorus rem oval system in the presence of roxarsone, and the consequencing biotransformation of roxarsone. The main conclusions are: (1) Short-term experiments show that roxarsone exhibits inhibitory effect on biological phosphorus removal process , especially for the phosphorus uptake processes. When roxarsone concentration is higher than 80 mg L-1, the reactor failed to accomplish phosphorus removal; By inhibiting model of PO43--P release and PO43--P uptake were analyzed, and discover that when roxarsone concentration less than 40 mg L-1, roxarsone on the inhibitory effect of PO43--P release rate was bigger, and when the concentration more than 40 mg L-1, inhibitory effect on PO43--P uptake is bigger. (2) Long-term experiments show that roxarsone inhibit the biological phosphorus removal process, resulting the increasing of sludge particle size, sedimentation rate, compactness, gray and complexity increase. No significant effect on the morphology of protozoan coul