全国大学生创新创业年会.DOC

H2O2的电化学合成及其在有机物 降解中的应用 哈尔滨工业大学 丁雅妮 （哈尔滨工业大学 能源科学与工程学院，黑龙江 哈尔滨 150001） 指导教师：高继慧 教授 ——————————————————————————————————————— 中文摘要：电-Fenton体系是一种重要的高级氧化体系，可原位生产H2O2和强氧化性?OH，被广泛应用于有机废水处理。但该体系H2O2产量较低，限制了进一步的发展。本文解耦并分析了H2O2在该体系中产生及无效分解的主要路径，首次提出利用脉冲电流抑制H2O2无效电还原分解路径，并研究了脉冲电流频率对H2O2产量的影响；同时，采用简易阳极氧化法对炭材料阴极进行改性以提高其反应活性，利用XPS分析、电化学测试等对其结构、性能进行表征。结果表明，采用脉冲电流最高可使体相H2O2浓度提高122.2%；采用阳极氧化方法改性炭材料阴极，可使H2O2产量提高183%。将上述两种策略实际应用在电-Fenton体系中降解布洛芬、活性蓝19等有机污染物，相比于对照组分别提高了53.8%、212%的降解率。 英文摘要：The electric-Fenton system is an important advanced oxidation system, which can produce H2O2 and strong oxidizing ?OH in situ, and is widely used in organic wastewater treatment. However, the lower production of H2O2 limits the further development. This paper decouples and analyzes the main path of H2O2 generation and ineffective decomposition in this system. It is proposed for the first time to suppress the H2O2 ineffective electric reduction decomposition path by pulse current, and study the pulse current frequency. The effect on the production of H2O2; at the same time, the cathode of carbon material was modified by simple anodizing method to improve its reactivity, and its structure and properties were characterized by XPS analysis and electrochemical test. The results show that the highest pulse current can increase the bulk H2O2 concentration by 122.2%. The anodizing method can modify the carbon material cathode to increase the H2O2 yield by 183%. The above two strategies were actually applied in the electric-Fenton system to degrade organic pollutants such as ibuprofen and reactive blue 19, which increased the degradation rate by 53.8%、212% compared with the control group. （已发表于Environmental Science and Pollution Research, 2018； Chemical Engineering Journal, 2017； Journal of the Taiwan Institute of Chemical Engineers, 2017） ———————————————————————————————————————