锂离子电池正极材料LiFePO4制备与石墨烯掺杂改性的研究-工程硕士专业毕业论文.docxVIP

种方法制备的磷酸铁锂正极材料均存在团聚现象。固相法制备的 种方法制备的磷酸铁锂正极材料均存在团聚现象。固相法制备的 磷酸铁锂比水热法制备的磷酸铁锂具有更高的充放电比容量，且在高 倍率下循环时的性能也比水热法的好。使用固相法制备的磷酸铁锂放 电比容量136mAh／g，而使用水热法制备的磷酸铁锂放电容量为 126mAh／g左右。 最后，通过掺杂石墨烯研究对磷酸铁锂正极材料的影响。通过观 察XRD图谱和SEM图谱，可以发现当加入5％的石墨烯时，不会影 响磷酸铁锂的生成，而当加入量为10％时，由于石墨烯易堆叠导致其 形成了石墨，在图谱上能明显观察到石墨的峰。加入5％石墨烯的磷 酸铁锂在低倍率下放电比容量能达到150mAh／g，同时高倍率下放电 比容量达到了1 10mAh／g，相较于未加入石墨烯的磷酸铁锂有一定程 度的提高。而当加入石墨烯过量时，由于活性物质相对减少，反而会 造成充放电比容量下降。加入石墨烯可以提高样品的导电性，减小极 化作用，减小材料的电荷转移阻抗，实现大倍率放电，提高样品的电 化学性能。 关键词：正极材料LiFeP04固相法水热法石墨烯掺杂 电 化学性能 万方数据 PREPARATION PREPARATION OF LiFeP04 CATHODE MATERIAL S AND STUDY OF LiFeP04／GRAPHENE AB STRACT Since the LiFeP04 has hilgh specific capacity which is 1 70mAh／g，it attracted wide attention and research by a lot of researchers．However, lithium iron phosphate has some shortcomings such as low electronic conductivity,low lithium ion diffusion coefficient and low tap density, which hinder its large—scale commercial applications．By using different methods for preparing lithium iron phosphate cathode material，and doped graphene，hoping to find the right conditions to improve the electrochemical properties of lithium iron phosphate． First，using hydrothermal method to synthesis lithium iron phosphate cathode material．There are a lot of factors which affect the hydrothermal method such as different pH values、different reaction time，SO we prepared four different pH values samples which pH value is 4、8、9、1 0 then compared their properties．We fred that the sample synthesized wiⅡ1 pH value of 1 0 has the highest discharge capacity and best cycle performance than the other three samples，indicating that under alkaline conditions will produce a good electrochemical properties of lithium iron III 万方数据 phosphate．Then phosphate．Then we study the influence of different reaction time on lithium iron phosphate．By contrast four samples synthesized in 5h，1 0h， 1 5h and 20h we found that the samples prepared in 1 5h and 20h have the best properties，suggesting the best time of hydrothermal method was 15h~2