离子液体介入的烯类、乳酸酯类可再生资源的催化转化-有机化学专业毕业论文.docxVIP

ABSTRACTTransfotination ABSTRACT Transfotination of biomass and derivatives thereof into valuable chemicals has been paid more attention during the past decade due to the inevitable decline in available fossil resources．Moreover,ionic liquids (ILs)commonly used as environmentally benign media，catalysts or additives，have exhibited their potential in the field of organic synthesis． Anethole is the major constituent of the essential oils usually extracted from star anise，anise seed or sweet fennel．0【-Pinene，the main component of turoentineoentine oils．’particularlyoils IS a particularly valuablevaluable and。anO inexpensive renewable resource．Ethyl lactate can be produced by fermentation of different carbohydrates(i e glucose and starch)and esterification．Therefore，the use of readily available biomass-derived olefin and ethyl lactate in the synthesis of high value-added fine chemical products is of extraordinary jml1 nce．Herein。Herein ionic llqmd-medlatediquid mediated catalyticcatalytic transformatictransformations OI anethole，O【．pinene and ethyl lactate were investigated and good results were obtained and the main contents of the thesis are summarized in the following： (1)A series of nano／microscale copper metal—organic frameworks were conveniently prepared via hydrothermal method or precipitation route and characterized by FT—IR，TG and TEM，respectively．The effects of catalyst，additive，solvent type and amount on the oxidation of anethole III 万方数据 to to anisaldehyde were investigated systematically．It was found that Cu—BTC-1 obtained from H3BTC ligands exhibited beRer performance． Notably，amphiphilic[C l 2mim]C1 is beneficial to the improved stability and good reusability of nano／microscale Cu-BTC-1．Under the optimum conditions，74．8％一9 1．5％conversion of anethole and 93．5％-94．6％ selectivity for anisaldehyde can be achieved over Cu-—BTC--1 with the aid of ionic liquid[C lEmim]C1．Additionally,nano／microscale Cu-BTC-1 exhibited good reusability，as supported by experimen