富含中、微孔稻壳活性炭的表征及液相吸附性能-中国环境科学.PDFVIP

中国环境科学 2010,30(12) ：1597~1601 China Environmental Science 富含中、微孔稻壳活性炭的表征及液相吸附性能 李大伟,朱锡锋* ( 中国科学技术大学,安徽省生物质洁净能源重点实验室,安徽 合肥 230026) 摘要：对采用 CO -NaOH 联合活化新工艺制备的稻壳活性炭的孔结构进行了表征,并用探针分子亚甲基蓝、苯酚考察了它对大、小分 2 的液相吸附性能.结果表明:所得活性炭同时富含中孔与微孔,中、微孔容积均达到 0.32cm3/g,各占总孔容的 50%;它对苯酚及亚甲基蓝均显 示出优越的吸附性能,脱除效率分别达到 94%和 99%,超过或接近所用优质商业活性炭的相应值;对这 2 种污染物的吸附皆较好地符合 Langmuir 等温式. 关键词：活性炭；苯酚；亚甲基蓝；稻壳；污水处理 中图分类号：X703.1 文献标识码：A 文章编号：1000-6923(2010)12-1597-05 Characterization and adsorption performance of micro-mesoporous rice husk active carbon. LI Da-wei, ZHU * Xi-feng (Key Laboratory for Biomass Clean Energy of Anhui Province, University of Science and Technology of China, Hefei 230026, China). China Environmental Science, 2010,30(12)：1597~1601 Abstract ：Attempts were made to characterize the pore structure of rice husk active carbon prepared by a new combined activation of CO2 and NaOH, and to investigate its adsorption toward large and small molecules by using methylene blue and phenol as probe molecules. The results showed that the micropore and mesopore volume both reached 0.32cm3/g and each accounted for 50% of the total pore volume, which indicated the abundance of both micropores and mesopores in the active carbon. The active carbon displayed strong adsorption ability. The removal percentages reached 94% for phenol and 99% for methylene blue. These values were comparable to those of the excellent commercial active carbon. Besides, adsorption of the two pollutants onto the active carbon both well followed the Langmuir isotherm. Key words ：active carbon ；phenol ；methylene blue ；rice husk ；wastewater treatment 印染废水是一种日排放量高、污染性强且难 度分子的工业废水提供参考. 处理的工业废水[1],常常同时含有大、小分子污染 1 材料与方法 物, 目前重要处理技术之一是用活性炭吸附.然而, 商业活性炭通常用煤、木炭等较贵原料制成[2],