毕业论文：淀粉基生物降解膜的制备及表征.docVIP

lw lw lw 化工与材料工程学院毕业论文 淀粉基生物降解膜的制备及表征 Preparation and Characterization of Starch-based Biodegradable Film 学生学号 学生姓名 专业班级 高分子材料与工程 指导教师 教 授 联合指导教师 完成日期 年6月12日 吉林化工学院 Jilin Institute of Chemical Technology lw lw lw 摘　　要 近年来，由于塑料垃圾造成的环境污染问题和石油危机给塑料工业带来的巨大压力，使得对可降解塑料的开发成为世界各国竞相研究的热点领域。淀粉是来源广泛的天然高分子，具有价格低廉、可再生、可生物降解等优点。已被公认为是最具有发展潜力的生物降解塑料的原料。然而由于其自身的多羟基结构和结晶规整排列等结构因素，限制了淀粉基生物降解膜的使用性能，特别是耐水性总是居高不下。 对此关键技术难题，本论文以淀粉为原料，PVA为增强剂，甘油为增塑剂，乙二醛为交联剂，尿素、纳米SiO2为耐水剂。采用流延交联法制备淀粉基生物降解膜。考察了物料配比、成膜介质、反应温度、搅拌速度等因素对可降解膜性能的影响。确定了适宜的合成工艺。解决了以往淀粉基生物降解膜耐水性差的技术难题，制得的淀粉基生物降解膜的吸水率低于72.8%，拓宽了淀粉基生物降解膜的应用性能。并对传统生物降解膜的降解实验方法进行了改进。 关键词：淀粉；PVA；生物降解膜；耐水性 Abstract In recent years, as a result of environmental pollution caused by plastic litter and the petroleum crisis in the plastics industry to the enormous pressure on the development of degradable plastics around the world compete to become a hot area of research. Starch is the source of a wide range of natural polymers, with a good many virtue for low cost, renewable, biodegradable, and so on.It Has been recognized as the most potential for development of biodegradable plastics raw materials. However, in virtue of its own structure and crystallization of polyhydroxy structured with structural factors such as limited biodegradable starch-based film performance, in particular, water resistance is always high. Withal This key technical problems,As raw materials for starch, PVA as a reinforcing agent, glycerol as a plasticizer, as crosslinker glyoxal, urea, water-resistant agents for nano-SiO2 in this paper. Examined the ratio of materials, film-forming medium, reaction temperature, stirring speed and other factors may affect the degradation of membrane performance. To determine the suitability of the synthetic process. To resolve the past biodegradable starch-based film with poor water resistance of technical problems, Obtained biodegradable starch-based films is lower than 72.8% water absorption. Traditional a