三元硼化物硬质合金覆层材料体系优化的研究-材料学专业论文.docxVIP

三元硼化物硬质合金覆层材料体系优化的研究裂和钢基体的屈服断裂的复合断裂特征。研究了碳化物添加量对覆层材料的弯曲强度 三元硼化物硬质合金覆层材料体系优化的研究 裂和钢基体的屈服断裂的复合断裂特征。研究了碳化物添加量对覆层材料的弯曲强度 的影响。采用干摩擦磨损与冲蚀磨损两种方式研究了硬质合金覆层材料的摩擦磨损特 性，结果表明，与单硬质相覆层材料相比较，所研制的六类硬质合金覆层材料的耐磨 性均有不同程度地提高。研究了覆层材料的耐腐蚀性能，结果表明，硬质合金覆层具 有比钢基体优越的耐腐蚀性。 研究了硬质合金覆层材料中的物相组成、硬质相与粘结相的分布状态、碳化物与 三元硼化物的界面特征以及覆层与基体的界面结合特征；研究了烧结工艺参数对硬质 合金．钢覆层材料显微组织结构的影响。提出了对硬质合金覆层材料扩散界面区域范 围的划分，并通过线扫描图像与覆层．钢基体结合界面显微硬度的测试分析了界面过 渡区的形成机理。 初步将硬质合金覆层材料应用于易磨易蚀的机械零件表面，成功制备了部分硬质 合金覆层零件。 关键词：硬质合金，覆层材料，真空液相烧结，力学性能，耐磨损与耐腐蚀性能。 Ⅱ 济南大学硕十学竹论文Abstract 济南大学硕十学竹论文 Abstract The researches were studied based 011 the preparation of the ternary boride hard alloy clad on the steel substrate successfully in this thesis．The structure with single hard phase in the hard alloy cladding materials was broken through by optimizing the material system． And a novel hard alloy cladding material with hi【gh hardness,excellent wear and corrosion resistance was developed by vacuum liquid phase sintering technique,which is with more hard phase cladding materials including the ternary boride and carbide clad on the side of the steel．It was applied in the field of improving the surface of the machine accessories， and better effects were obtalned． The new type of hard alloy cladding material system was optimized through the research method of material thermodynamics and diffusion kinetic．Six types of cladding materials had been developed successfully on the side of steel for the first time，which were designated W；C E CW；TC and WTC respectively．The basic chemical compositions and the contents of alloy elements Cr,Ni，adhesive PVB in cladding were determined．The technology process of the preparation of the hard alloy cladding materials was established, which included four parts：the technology of the preparation of the slurry,disposal technology of the steel substrate，molding mode of the cladding green piece and the sintering technology of the cladding materials．The effect of the sintering ambience， temperature increasing velocity,the higllest si