三维电极催化氧化降解废水中γ六六六的新方法-分析化学专业论文.docxVIP

中山大学硕士学位论文时，Y一六六六降解率已达70％，脱氯率已达89％。 中山大学硕士学位论文 时，Y一六六六降解率已达70％，脱氯率已达89％。 4．在本电催化处理Y．六六六实验条件下，通过用GC—MS检测中问产物实验 和用离子色谱检测生成的游离氯离子实验表明，Y．六六六的降解机理是先降解 成1，3，4，5,6．五氯环己烯和氯离子，随后逐步降解为其它含氯形式更低的脱 氯产物。 关键词：Y一六六六 三维电极法 催化氧化 持久性有机污染物 降解机理 Ⅱ 中山大学硕士学位论文A 中山大学硕士学位论文 A new method of degradation of 7-HCH in waste water catal)rzed and oxidated by three dimension electrode Major：Analytical Chemistry Name：Zhang Liang Supervisor：Asso．Prof．Chen Weiguo Abstract Hexachloro—cyclohexanes(HCHs)have been used globally pesticides．As one kind of genus persistent organic pollutants(POPs)，they also have the characteristics of non-biodegradation，persistence，bioaccumulation and bio—toxicity both in wild animals and human beings．For seeking the life of healthier and happier in Green-age now it is becoming hot problem that scientists study removing these POPs from environmental media such water,soil and sediment． In this study,one kind of genus POPs，Y—HCH in water catalyzed and oxidated by three dimension electrode method was explored to find more economical and practical method to remove POPs．The paper studied the infection of some physical and chemical factors to the degradation of Y-HCH in water catalyzed and oxidated by three dimension electrode method for the first time．The study approved that y ·HCH can be degraded by three dimension electrode method efficiently．The paper studied the degradation mechanism of y—HCH in water elementarily,thus formed a new method to remove trace Y-HCH by three dimension electrode method．The results were as following： 1．The experiment about catalyzer adsorption showed that catalyzer can adsorb y ·HCH in waste water,the value of adsorption saturation was 1．646×104mg／mg，SO catalyzer should be saturated before degradation． 2．The degradation mechanism of Y—HCH in the experiment showed that it was first order kinetics reaction．The react rate constants were different at dififerent temperature，that wag k40℃k35℃k25℃，they were among O．035一O．042min-1：as to halflife．the order wa