三维电级改性催化填料的研制及在处理有机废水中的应用-分析化学专业论文.docxVIP

{}毕杰 {}毕杰 t{t山大学颧士学位沧文 本文不仅为实现三维电极利用改憔催化剂填料掇i笥处理有机废水效率提供 理论依据，同时还为工业生产实际操作的技术参数的确定提供了详实而可靠的摹 戳数摄。 关键词：纳米材料，催化剂，三维电极，羟基自由基，有机废水处理 U ————垦兰鱼—燮望窭兰鲎整鎏耋——P。eparation ————垦兰鱼—燮望窭兰鲎整鎏耋—— P。eparation of modifieative three-dimension electrode eatalyst filler and its application in treatment of organic wastew建te} Major：Analytical Chemistry Name：Gan鞋驻硒ie Supervisor：Associate professor Chen Weiguo Abstraet This thesis makes a comprehensive and systematic study on the preparation of modificative three—dimension electrode catalyst filler and its application in electric catalysis oxidation of four types of organic pollutants including phenol，aniline，potassium biphthalate and isopropanol by three-dimension electrode technology。 First，a new method of preparation three-dimension electrode catalyst filler was investigated，This modificative filler makes up of pulverous active carbon，nano metal oxide and the§巍l菇塔agent． Second，the effect of the main physicochemical factors，including the ceil voltage，pH value and treating time，On the removal rate of the contaminants was fully investigated． Third，this study focus On the comparison of performance of two kinds of fillers，which are made up of different catalyst，in the treatment organic wastewater+The experimental results show that the modification catalyst filler can more efficiently remove organic compounds and has the higher COD removal rate than the fillers currently used after l 0 minutes， Fourth,the mectmnism of the organic pollutants degradation m the three-dimension electrode was studied by U职IR，GC and other instrumental analysis+Results indicate that they are mainly destl。oyed 111 ——I!些查!坐查堂黧!：堂竺鎏兰by ——I!些查!坐查堂黧!：堂竺鎏兰 by the oxidation of hydroxyl radical． In conclusion，the research work in preparation of modificative catalyst filler and its application in treatment these four kinds of or窑a琏ic pollutants not oray serves as a theoretical basis to enhance the efficiency of the three。dimension electrode to treat such wastewater，but ats