锂离子电池负极材料的制备及其改性研究-应用化学专业论文.docx

锂离子电池负极材料的制备及其改性研究 中文摘要 锂离子电池负极材料的制备及其改性研究 中文摘要 四氧化三钴（Co3O4）负极材料因为具有较高的理论比容量（890 mA h g-1），因 此引起了人们的广泛关注。本文通过改变pH值和尿素含量，采用水热-热分解法合成 了不同形貌的Co3O4材料，分别为Co3O4-leaf，Co3O4-sheet，Co3O4-cube。通过SEM， CV，EIS，循环和倍率性能等一系列表征，我们得出Co3O4-leaf由于具有超薄结构， 有利于锂离子扩散和电子传输，因此具有最好的电化学性能。 Ni0.5TiOPO4由于具有较高的能量密度，价格低和良好的热稳定性而受到人们的关 注。但是和磷酸盐类的正极材料一样，这一类材料的缺点仍然是低电子电导率。本文 通过Cu2+掺杂和制备纳米级的Ni0.5TiOPO4来改善电子电导率，提高材料的循环性能和 倍率性能。实验结果表明Cu2+掺杂和纳米化的Ni0.5TiOPO4均能在一定程度上提高循环 性能和倍率性能。 LiTiOPO4和Ni0.5TiOPO4同属于一种类型的磷酸盐类化合物，但是目前文献中， 还没有LiTiOPO4作为锂离子电池负极材料的报道，为了探讨与Ni0.5TiOPO4的异同之 处，我们把LiTiOPO4作为负极材料应用于锂离子电池中。由于LiTiOPO4同样存在电 子电导率差的问题。本文以葡萄糖和PVDF为碳源，对其进行碳包覆改性。实验结果 表明，经过碳包覆的LiTiOPO4性能得到了很大程度的提高。 关键词：锂离子电池；负极材料；Co3O4；Ni0.5TiOPO4；LiTiOPO4；改性 作 者：金玲玲 指导教师：郑军伟 教授 李晓伟 博士 I 英文摘要 锂离子电池负极材料的制备及其改性研究 The preparation and modification of the anode materials for Li-ion battery Abstract Cobalt Oxide (Co3O4) has attracted an increasing amount of attention due to its high theoretical capacity of 890 mA h g-1. We implement a hydrothermal route to prepare the different morphologies of Co3O4 products. It is found that the urea and the pH play a key role in controlling the formation of the different morphologies of Co3O4. Through SEM, CV, EIS, cycling performances and rate capability, we can conclude that the ultra-thin structure facilitates the diffusion of lithium ions and electrons, which makes Co3O4 owing the best electrochemical performance. Ni0.5TiOPO4 has higher energy densities, lower price and better thermal stability, so it attracts much attention for use as anode materials for LIBs. However, as many of phosphates, Ni0.5TiOPO4 exhibits a low electronic conductivity reducing notably its electrochemical performances. In this paper, we modify the electronic conductivity by doping the Cu2+ ions and preparing the nanoparticle of the Ni0.5TiOPO4, which could increase the cycling performance and the rate capability. The result shows that the Cu2+ doped and the nanoparticle can also improve the cycling performance and the