流化床制备复合颗粒的分析-化学工艺专业论文.docxVIP

南京理T人学f{j：{卜学位论义 南京理T人学f{j：{卜学位论义 流化床制备复台颗粒的研究 摘要 为了对颗粒表面进行改性，在自行设计组装的流化床反应器中，利用化学气相沉 积法(cvDl制备了不同的复合颗粒。以四氯化钛(TiCl4)为前驱体，制备了硅胶负载二 氧化钛(Ti02)复合颗粒，考察了反应时间对二氧化钛沉积量的影响，研究了复合颗粒 在紫外光下对草酸的催化降解功能。用扫描电镜(SEM)*n特征x射线能谱仪(EDS)对 复合颗粒表面进行了表征，发现复合颗粒表面均匀性和均一性都比较好，二氧化钛颗 粒分为微米级和纳米级两种。沉积量随反应时间的增加而增大，但存在最大值，复合 颗粒的光催化性能良好。以钛酸丁酯(Ti(OC4H7)4)和硅酸乙酯(Sj(0C2H5)4)为前驱体， 分别制备了二氧化钛和二氧化硅包覆硅胶颗粒，SEM检测发现复合颗粒为成膜包覆， 但存在包覆量较少的问题。以四氯化钛为前驱体对不同粒径的铝粉进行了包覆处理， 考察了水和萨丁醇(C4H70H)对铝粉进行表面预处理对复合效果的影响，复合颗粒经 SEM和EDS表征，结果发现铝粉表面实现了二氧化钛颗粒层包覆。经表面预处理的 铝粉制备的复合颗粒，表面沉积的二氧化钛粒径变小，包覆层更加均匀。 关键词：流化床 复合颗粒 包覆 二氧化钛化学气相沉积铝粉 摘婆 摘婆 硕十论文 Abstract In order tO modify the surface properties of the particles，composite particles are prepared by the process of Chemical Vapor Deposition(CVD)in a fluidized bed reactor． Silica gel particles loaded Ti02 were obtained by using TiCl4 as precurson The relation between the deposition weight of Ti02 and time Was studied．The photocatalytic performance of composite particles Was also evalumed by the degradation of oxalic acid under the ultraviolet radiation．SEM and EDS were used to characterize the surface structural properties of composite particles．n was found that the deposited Ti02 in nanometer and micrometer range，which was on the surface of Silica gel particles，was uniform．The deposition weight of Ti02 increased as the reaction time prolonged，but a maximum existed in the process．The photocatalytic performance of composite particles WaS excellent．By using Ti(OC4HT)4 and 8i(OC2H5)4 as precursors，silica particles coated by Ti02 and Si02 film were prepared，respectively．But only fewer composite particles were obtained due tO the little deposition quantity of Ti02 and Si02．Aluminum particles coated by Ti02 were prepared by using TICl4 as precurson The effect of the pretreatment of Aluminum particles by H20 and C4H70H on the composite particles was studied， respectively．SEM and EDS analysis indicated that aluminum particles had coated by Ti02 successfully．The size of Ti02 on the surface of modified alumin