六角晶系铁氧体空心微球的制备与性能研究-材料学专业论文.docxVIP

武汉理工大学硕士学位论文Abstract 武汉理工大学硕士学位论文 Abstract Ferrites are conventional wave absorbing materials，which have such advantages as strong absorption，simple techniques and cheap raw materials，but they are quite heavy and have difficulties in increasing the permeability in GHz region．Hollow ferrites particles are the alternative to conventional solid ferrites particles，which have lower density,larger specific surface area and stability．Moreover，it is expected electromagnetic wave can be reflected and absorbed again and again in the cavum of hollow particles which become its black hole．In addition，their electromagnetic parameters can be aajusted in a certain range by changing the thickness of the shell and the diameter of hollow microspheres，and the ability of absorbing microwave Call be expected to improve．Wave absorbing materials of hollow structure are the research trend． In this thesis，the structure and basic characteristic of hexagonal ferrite absorbent were summarized，and popular methods to prepare ultrafine ferrite particles and hollow microspheres were introduced． Hexagonal ferrite hollow microspheres were prepared by flame powders spraying technique and flame suspending solution spraying technique．The phase component，microstructure and electromagnetic properties of the synthesized hollow microspheres were studied as functions of heat—treated techniques(1ike temperature，time，the speed of heating)in detail． W—type BaC02Fel6027 and M—type BaFel20i9 hexagonal ferrite hollow microspheres were fabricated by flame powders spraying technique using oxygen and acetylene as fuel．The method resulted in abroad particle size distribution(mainly from 4 la m to 20 u m)，and the density was about 2．50 g／cm3．The process of heat—treatment showed M—type ferrite was straightly formed from metal oxide without the transition of spinel phase．The formation process of W-type ferrite underwent from oxide of metal，the M—type transition phase to final W-phase．When the heating rate was 5*C