响应面优化制备粉煤灰基PASC混凝剂性能与表征.PDFVIP

中国环境科学 2018,38(12) ：4599~4607 China Environmental Science 响应面优化制备粉煤灰基 PASC 混凝剂性能与表征 劳德平 1,丁书强 2∗,倪 文 1,李晓光 2,李佳洁 1,高光辉 2 (1.北京科技大学土木与资源工程学院,北京 100083 ；2.北京低 碳清洁能源研究院,北京 102211) 摘要：研究了以粉煤灰为原料制备聚硅氯化铝(PASC)混凝剂的影响因素、产品性能和微观结构.选取 A (碱化度) 、B(n(Si):n(Al))、C(聚合温度) D(反 应时间)对混凝高岭土模拟废水后透光率进行四因素三水平响应面实验.最终优化方案为:A 为 1.18,B 为 5.64,C 为 47.40 ℃,D 为 2.48h,透光率预测值达 86.58%,验证试验均值相对误差仅为 0.18%,模型相关系数为 0.9984,表明 RSM 优化模型可靠.混凝剂性能随投加量增加而不断增加,最终趋于稳定;随废 水 pH 值增大呈现先增大后减小的趋势.XRD 分析 PASC 主要物相为氯化钠,非晶态衍射峰形成预示着浸出液和聚硅酸加碱聚合形成了新的无定形 物;FT-IR 测试表明聚硅酸与 Al3+及其水解产物间络合形成了金属-OH 等非离子键;SEM 显示产品为高聚集度和枝化度的空间网状结构. 关键词：粉煤灰；聚硅氯化铝(PASC) ；响应面(RSM) ；聚硅酸 中图分类号：X752 文献标识码：A 文章编号：1000-6923(2018)12-4599-09 Response surface method optimization of preparation fly ash based polysilicate aluminum chloride coagulant: performance and microstructure characterization. LAO De-ping1 2∗ 1 2 1 2 , DING Shu-qiang , NI Wen , LI Xiao-guang , LI Jia-jie , GAO Guang-hui (1.School of Civil and Resource Engineering, University of Science and Technology Beijing, Beijing 100083, China ；2.National Institute of Clean and Low Carbon Energy, Beijing 102211, China). China Environmental Science, 2018,38(12)：4599~4607 Abstract ：This paper investigates the factors that influence the preparation of polysilicate aluminum chloride coagulant using coal fly ash and their performance and microstructure. Four factors(basicity, n(Si): n(Al), polymerization temperature and reaction time) and three levels of response surface experiments were carried out, which regarded the transmittance of Kaolin simulated wastewater as the evaluation index. Results show that the optimum scheme when the basicity was 1.18, the n(Si):n(Al) was 5.64, the polymerization temperature was 47.40°C, and t