硫酸锰制备四氧化三锰及其热解动力学研究-化学工艺专业论文.docxVIP

琉■【誊倒●·四●L1性—l反其期!算t九力尊u日t观活化能为117．11 琉■【誊倒●·四●L1性—l反其期!算t九力尊u日t 观活化能为117．11 kJ·mol一。750℃．1050℃之间为MnS04的分解阶段，积 分动力学机理函数为G(a)=l-(1-a)忱，符合相边界反应的收缩圆柱体模型， 平均表观活化能为226．44 kJ·tool1；MnS04等温分解结果与TG-DSC分析结 果一致。 对硫酸锰制备Mn304及其热解动力学的研究结果，可为硫酸锰制备 Mn304的工业化生产提供基础数据和理论依据。 关键词：硫酸锰四氧化三锰两段氧化热解动力学 Ⅱ 翌竺壁型苎—-!型竺型竺型塑竺坚PREPARATION 翌竺壁型苎—-!型竺型竺型塑竺坚 PREPARATION OF HAUSMANNITE BY MANGANESE SULPHATE AND THE KINERICS OF ITS THERMAL DECOMPOSITION ABSTRACT Fenite is彻e l【ind of soft magnetic matmal which is widely used in commllllic砒ioIlthe audio and video equipment,power switch and magnetic hcad岫，眦Hausmannite is the main material to produce ferrite·Now h锄1smannite is讲唧哪司by electrolyzing manganese metal in our country,the cost of tllis m甜10d is high because of the面ce of the nmnganese and the po钟 of i乜p删6t2喊l时．In this paper Hausmannite was respectively pr印a删by a me吐lod of伽o stage oxidation and thermal decomposition of solid phase us．m．g m锄gane辩跚lpI曲蠲∞atefial．The reaction temperature,the velocity ofMll2+ Ⅱ旧眦io of the孤mn耐a to Mn2+，drying temperature and drying time that 颤fe：cted n拉a叫ltem of the manganese in the samples were discussed through 豳西e factor experiments and orthogonal叫，cr岫朗It．The optimum倒1diti鲫is that thc枷o of也e舢砌a to舻is 2：1，the addition rate of Mn2+is 30 mL．h-I．the reaction temperature is 95℃，the蜘teI印咖is 200℃and ili ，1■j—簟硪士掌位论文 ，1■j—簟硪士掌位论文 硫It■¨■●P曩簟-’匕三ta囊；茹!舅：薯’力孽啊开，t the drying time is 3 h by experiments．It confined that the product was y-Mn304by using XRD analyzed the sample，the content ofthe m姐g锄【e∞was 71．1 0％，the average size ofthe powders was 1．23Ⅲ盼in the optimum condition． In preparation ofhausmannite by thermal decomposition ofmanganese sulphate, the calcining temperature，the calcining time，the cooling pattern of the sample were discussed through single facttor experiments and orthogonal experiment． The optimunl condition is that the calcining temperature is 1000℃，the calcining time is 2 h and the cooling pattern of sample is cooling produ