炼油污水深度吸附脱氮技术研究-环境工程专业论文.docxVIP

Study Study on Removing Ammonia Nitrogen Further from Refinery Wastewater by Adsorption Method Abstract In this Paper the adsorption method with modified clinoptil01ite and modified rectorite is studied for depth removal of ammonia nitrogen in the refinery bio-treated wastewater．Several factors such as the adsorption ability of ammonia nitrogen and the price of adsorbents were studied together to give the high quality adsorbents--cIinoptilolite and rectorite． These two adsorbents were modified further to find the best method to improve their adsorption abilities．The results showed that clinoptilolite which is soaked by 2mol／L NaOH．heated at 90℃for 8 hours is the best．And Na—rectorite which is treated with alumini啪s01 first．then heated to 300℃．following being soaked by O．2mol／L NaOH behave best． In the research of adsorption capability of ammonia nitrogen，the results showed that the cations coexisting in the refinery wastewater are the main factors affecting the adsorption of Nl-h+-N on modified clinoptiloIite．The increasing of tempemture makes the adsorption rate faster．And when temperature is higher than 25℃，the adsorption rate increases slowly． The best effect is got when pH is 5-7．The equilibrium adsorption content every unit weight increases with the increasing of ammonia nitrogen concentration and decreases with the increasing of the adsorbents’ amount．In也e refinery wastewater，the adsorption of ammoma nitrogen oil modified clinopfil01ite and modified rectorite can be well described by Langmuir and Freundlich adsorption models．The adsorption of ammoma nitrogen on modified clinoptil01ite is a process that film diffusion contr01． The ammonia nitrogen concentration in the refinery wastewater can be decreased from 24．6 mg／L to l mg／L through the adsorption column packed with the modified C1inopfilolite．The modified clinoptil01ite can be regeneration after getting adsorption equilibrium by mixing solution which contains 0．4m01，I烈aOH and 10％NaCl． Key Key Wo