基于SAP 吸水膨胀橡胶的耐温耐盐性能.PDF

SA P 33 SAP Study on T hermal/ Salty T olerance of SAP-based Water Swelling Rubber , , , ( , 43 73) LI Xiu-hui, WU Jiang-yu, YANG Peng, GUO San-w ei ( School of Materials Science and Engineering, Wuhan Institute of T echnology, Wuhan 43 73, China) : P(AANa/ AMPS/ DMDAAC) ( SAP) , SAP , , ( WSR) WSR , WSR : , , WSR , ; WSR , WSR 12 175 , WSR : ; ; ; ; : T Q336 : A : 1 1-4381( 2 1 ) 4- 33- 3 Abstract: Superabsorbent polymer ( SAP) of P( AAN a/ AMPS/ DM DAAC) w as synthesized by inverse suspension polymerization. Hydrophobic modification of this SAP w as performed v i a i n-s it u polymer-i zation w ith introduced monomer n-butyl acrylate and acrylic acid. Water sw ellable rubber ( WSR) w as prepared using modified SA P, NBR, reinforcing agent and other additives. T he swelling ratio in mass of WSR in w ater or in aqueous solutions of diverse inorganic salt w as measured. T he effects of ionic concentration and temperature on the sw elling ratio w ere investigated and thermogravimetric analysis (T GA) of sw ollen rubber w as performed. T he results show ed that the sw elling ratio of W SR remark- ably decreased w ith higher ions valence and w ith increasing concentration of salt solution. T he highest sw elling rate w as obtained at 12 , both in w ater and in . 9%NaCl solution. A w ater loss plateau of sw ollen WSR w as observed w ith . 9% NaCl solution as the absorbent solution. Key words:w ater sw ellable rubber; superabsorbent polymer; thermal stability; salt resistance; hydro- phobic modificati