锂离子电池三元Si基复合负极材料的研究-材料学专业论文.docxVIP

摘 要 随着新能源和新材料的开发和应用，关于锂离子电池电极材料的研究越来越得到重 视。硅具有比容量高 (理论比容量为 4200mAh/g) 和倍率放电性能好等优点，是目前锂电 负极材料研究的热点之一。 本文研究了 Mg-Ni-Si 和 Al-Ti-Si 两个不同体系复合负极材料的电化学规律。对于 Mg-Ni-Si 体系而言，Si 含量对电化学性能有明显影响。热处理可以有效提高 Si 含量样品 的循环性能和库伦效率。Si 含量（按摩尔比）为 15%时首次库伦效率为 64%左右，Si 含量 为 30%时，首次库伦效率为 52%左右。Si 含量（按摩尔比）小于 15%时，其含量每增加 5%，循环性能减小 7%左右；Si 含量超过 15%时，其含量的变化对循环性能产生较大的影 响。对于 Al-Ti-Si 体系而言，其充放电曲线显示样品经首次充放电后，由晶态转变为非晶 态。Al-Ti-Si 体系首次库仑效率较低，第二次循环以后库仑效率较高；但可逆容量较低。 对于样品 Al30Ti45Si25 经 700℃和 800℃烧结后循环性能较好。说明 700℃以上烧结对样品 的循环性能有明显的提升作用。 关键词：Mg-Ni-Si；Al-Ti-Si；负极材料；锂离子电池 - I - Abstract With the exploitation and application of new energy and new materials, much effort has been focused on investigation of new electrode materials. Si has a high specific capacity (4200 mA·h/g) and perfect rate discharge, so it has become one of the research hotspots of anode materials for lithium-ion batteries. In this paper, electrochemical properties of Mg-Ni-Si and Al-Ti-Si system anode composite has been investigated. For Mg-Ni-Si system, Si content has obvious influence on the electrochemical properties. Heat treatment can effectively increase the circulation performance and the coulomb efficiency of higher Si content sample. When Si content (according to the mole ratio) is 15%, the first coulomb efficiency is 64%; when Si content is 30%, the first coulomb efficiency is 52%. When Si content is less than 15%, the cycling performance reduces by 7% as the content of Si increasing by 5%. When Si content is more than 15%, the content of Si has greater effect on cycling performance. For Al-Ti-Si system, its charge-discharge curve shows samples change into amorphous from crystal after the first charging-discharging cycling. For Al-Ti-Si system, the first coulomb efficiency is low and then the second coulomb efficiency increases, but reversible capacity is low. Al30Ti45Si25 sample with 700 ℃ and 800 ℃ heart treatment has good cycle performance, showing the sample heat treatment above 700℃ has good cycling properties. Key Words：Mg-Ni