磷酸铝胶粘剂的制备及力学性能研究化学工程与技术专业论文.docxVIP

哈 哈尔滨工业大学工学硕士学位论文 - - II - Abstract Aluminum phosphate adhesive has the advantages of low curing temperature, excellent dielectric properties, non-toxicity, high binding strength and high temperature structural stability, and it has broad application in architecture and aerospace. In this article, analysis of viscosity, TG-DTA, FT-IR, XRD, SEM and bending strength were done, self-curing reaction of the aluminum phosphate matrix, curing reaction of the adhesive. Impacts on mechanical properties and curing temperature of different mass ratio of aluminum phosphate matrix and different curing agents were studied. Tests of bending strength and viscosity and mechanical properties revealed the best performance of strength properties of Al(H2PO4)3 matrix with different molar ratios of P and Al. Al(H2PO4)3 matrix reacted with itself at the temperature of initial curing temperature, which resulted in AlH2P3O10 and its form containing crystalized water. A molecular of H2O was abstracted between every two moleculars of P-O-H, in which a bond of P-O-P was formed in the shape of line. A hexagonal structure of Al(PO3)3 with P-O-P bond in its circle shape formed under complete curing temperature, which provides adhension. Hexagonal structure of Al(PO3)3 transformed into its cubic state at about 550℃. Al(H2PO4)3-Sintering Al(OH)3 adhesive with the aluminum phosphate matrix and curing agent mass ratio of 5:1 transformed into Al(HP2O7)·2.5H2O, under the complete curing temperature. Trigonal AlPO4 transformed into the rhombic system at a certain temperature. Adhension was provided by inorganic macromolecular linked by Al-O-P-O-Al. Al(H2PO4)3-Al(OH)3, Al(H2PO4)3-sintering Al(OH)3 and Al(H2PO4)3-Al2O3 adhesives with the matrix and curing agent mass ratios of 6:1, 7:1, 5:1 respectively transformed into AlPO4 and Al(PO3)3. Al(H2PO4)3-Fe2O3 adhesive with the matrix and curing agent mass ratios of 7:1 transformed into Fe(PO3)3, AlPO4 and Al(PO3)3. Al(H2PO4)3-CuO adhesive w