藻类有机质的组成结构对菲和壬基酚生物吸附的影响.PDF

２０１６年　 第 １１卷 生 态 毒 理 学 报 Vol. 11, 2016 第２期ꎬ６０２￣６０８ Asian Journal of Ecotoxicology No.2, 602￣608 DOI: 10.7524/AJE.1673￣5897.20151110002 张代男, 段丹丹, 杨余, 等. 藻类有机质的组成结构对菲和壬基酚生物吸附的影响[J]. 生态毒理学报ꎬ2016, 11(2): 602￣608 Zhang D N, Duan D D, Yang Y, et al. Composition and structure of algal organic matter and their effect on the biosorption of phenanthrene and nonyl￣ phenol [J]. Asian Journal of Ecotoxicology, 2016, 11(2): 602￣608 (in Chinese) 藻类有机质的组成结构对菲和壬基酚生物吸附的影响 张代男ꎬ 段丹丹ꎬ 杨余ꎬ 冉勇* 中国科学院广州地球化学研究所ꎬ广州510640 : : 收稿日期 2015￣11￣10 　 　 录用日期 2015￣12￣22 摘要:对不同来源藻及其有机级分进行元素分析ꎬ利用高级核磁共振技术(multi/CP 13 C NMR)来准确地定量其有机官能团ꎬ并 研究它们对菲和壬基酚的生物吸附行为和机理ꎮ 结果表明游离脂和非水解有机碳级分对菲和壬基酚有最高的吸附能力ꎬ其 吸附容量与脂肪结构呈极显著的正相关ꎬ而与极性官能团呈极显著的负相关ꎻ而且对壬基酚的吸附容量都大于对菲的吸附容 量ꎬ可以用专性作用(如π￣π键作用和氢键作用)来解释ꎮ 关键词:藻类有机质ꎻ菲ꎻ壬基酚ꎻ生物吸附 文章编号:1673￣5897 (2016 )2￣602￣07　 　 中图分类号:X 171.5　 　 文献标识码:A Ｃｏｍｐｏｓｉｔｉｏｎ ａｎｄ Ｓｔｒｕｃｔｕｒｅ ｏｆ Ａｌｇａｌ Ｏｒｇａｎｉｃ Ｍａｔｔｅｒ ａｎｄ Ｔｈｅｉｒ Ｅｆｆｅｃｔ ｏｎ ｔｈｅ Ｂｉｏｓｏｒｐｔｉｏｎ ｏｆ Ｐｈｅｎａｎｔｈｒｅｎｅ ａｎｄ Ｎｏｎｙｌｐｈｅｎｏｌ * Zhang Dainan, Duan Dandan, Yang Yu, Ran Yong Guangzhou Institute of Geochemistry, Chinese Academy of Sciences, Guangzhou 510640, China Ｒｅｃｅｉｖｅｄ 10 November 2015　 　 ａｃｃｅｐｔｅｄ22 December 2015 Ａｂｓｔｒａｃｔ:Different cultured and field￣collected algal specie samples were collected, selectively fractionated into different organic fractions, and quantitatively characterized by using advanced multi/CP 13 C NMR techniques. Their biosorption isotherms and mechanism for phenanthrene (Phen) and nonylphenol (NP) were investigated. The LP and NHC fractions exhibited the highest sorption capacities. The observed sorption capacities were highly positively correlated with aliphatic constituent and structure, but negatively related to their polar groups. The higher sorpt