粉状及造粒污泥的燃烧反应动力学研究.docVIP

中国工程热物理学会 燃烧学 学术会议论文 编号： 粉状及造粒污泥的燃烧反应动力学研究作者简介：刘薇 作者简介：刘薇 (1994-)，女，硕士研究生, 主要从事燃料反应动力学、大气污染物控制等方面研究。 刘薇1，张健1，张瑞娜2, 刘泽庆2, 曹瑞杰1, 穆艾伟1, 张忠孝1 （1.上海理工大学环境与建筑学院，上海 200093； 2.上海环境卫生工程设计院有限公司，上海 200232） 联系人：刘薇 联系电话摘 要 污泥是城市污水处理后产生的可燃污染物，需要大量处理；目前污泥与垃圾协同焚烧是常用的污泥处理方法。本文采用非等温热重分析方法,对多种粉状污泥原样测试其反应动力学特性（包括热解、焦炭-O2反应，焦炭-CO2反应），进而又试验研究了造粒污泥（成型）的燃烧过程。考虑造粒污泥的燃烧特性，可以理解在垃圾焚烧炉内污泥燃烧主要处于前侧的低温位置。通过实验得到的粉状污泥动力学数据，利用单膜模型与准静态假设，可以获得气体温度与焦炭颗粒温度的理论关联，利用该数据分析：焦炭颗粒不会发生颗粒温度着火与跃升现象；并且解释炉内未燃尽的污泥粉状（1#污泥）颗粒会在喉口处的高温火焰中呈现结焦倾向，与实测相符。此外，测试数据表明：干燥污泥中灰分含量占50wt%；污泥挥发分析出速率低于同温度的一般煤粉的情况；污泥中富含Fe元素，对污泥焦炭与氧气的燃烧速率有一定的催化提升作用。 关键词 污泥；反应动力学；热天平；垃圾焚烧炉；单膜模型。 Experimental investigation of kinetics of Pulverized and Briquette Sewage Sludge Samples Wei Liu1, Jian Zhang1, Rui-na Zhang2, Ze-qing Liu2, Rui-jie Cao1, Ai-wei Mu1, Zhongxiao Zhang1 (1.School of Environment and Architecture Engineering, University of Shanghai for Science and Technology, Shanghai, 200093, China;2.Shanghai Institute for design research on environmental engineering Co, Ltd. Shanghai, 200232 China) Abstract: Sewage sludge is a combustible pollutant as produced in sewage facility, which requires a lot of subsequent treatments, e.g. co-burning of sludges and wastes in an incinerator. The target of this paper is to clarify the kinetic characteristics of various pulverized sludge samples, (incl. pyrolysis, coke-O2 and coke-CO2 reactions) as well as the combustion process of the briquette sludge. Based on lab-scale experimental data, the combustion conditions in incinerator were analyzed. The relationship between flue-gas temperature and pulverized-coke temperature was discussed through the quasi-static assumption and single-film model. Furthermore, the volatile releasing rates are lower than those of common pulverized coals. And Fe in ash makes a certain role of catalytic impacts to enhance coke oxidization rate