酞菁氧钛的绿色合成和绿色转型与其应用分析.pdfVIP

ABSTRACT Oxotitanium phthalocyanine (TiOPc) is a widely used organic functional material. In the conventional synthesis methods, high-boiling organic solvents such as quinoline, tetralin, N-methylpyrrolidone, 1-chloronaphthalene and ortho-dichlorobenzene are used. These toxic solvents would produce chlorine or heterocyclic impurities, reducing the purity of TiOPc, increasing the difficulty of post-processing and causing security and environmental issues. The transformation of amorphous TiOPc using chlorobenzene, dichlorobenzene, chloronaphthalene and other halogen-containing organic solvents are also harmful to environment and human health. In this paper, polydimethylsiloxane (PDMS), dodecylbenzene and diphenyl methane were used as reaction solvent, tetrabutyl titanate and 1,3-diiminoisoindoline were used as raw materials for preparing oxotitanium phthalocyanine (TiOPc). The results showed that when using diphenyl methane as reaction solvent, the yeild of the product was the highest, and the post-processing was the easier than in the case of other solvents. The orthogonal experiment was applied to optimize the reaction conditions for preparing TiOPc in diphenyl methane. The optimal reaction conditions were reaction temperature 200 °C, reaction time 3 h, molar ratio of tetrabutyl titanate to 1,3-diiminoisoindoline 3.5: 1 and adding dropwise of tetrabutyl titanate in the reaction system at 120-130 °C. Under