衣康酸改质几丁质吸附巴拉刈之研究.ppt

根據圖6所知 36ppm之最低起始濃度下，其同時間吸附曲線斜率均比其他C e者大，顯示此自製吸附劑對於水溶液中低溶度PQ離子的吸附力，值得肯定。 圖7、在37.5℃時，吸附巴拉刈之FD等溫吸附線 圖8、圖6和圖7 等溫吸附線之比較 結論 1.PQ濃度測定檢量線之線性表示測定準確。 2.自製CT-g-IA吸附劑對於水溶液中低溶度PQ離子的吸附力，值得肯定。 3.根據以上實驗得知吸附結果確實優於現用的幾丁質、活性碳以及胃腸吸收劑。 4.證明本專題研製之新型巴拉刈吸附劑有其開發潛力，未來可能可應用於巴拉刈中毒病患之急救。 參考文獻 1. Khaled El-Tahlawy, Samuel M. Hudson ; Graft copolymerization of hydroxyethyl methacrylate onto Chitosan. J. Appl. Poly. Sci. Vol. 82, 683-702(2001) 2. J.Retuert and M. Yazdani-Pedram ; Cocatalyst effect in potassium per-sulfate initiated grafting onto Chitosan. ; Poly. Bulletin ,Vol.31, 559-562 (1993) 3. 徐新興，糜福龍; 海洋資源與化工技術－幾丁質與幾丁聚醣在化工領域之應用 ; 化工 第46卷第3期(1999) 4. 張聰明，蕭明裕，彭瓊輝，王文綺 ; 生物化學(Principles of Biochemistry)初版 ; 新文京開發出版有限公司 5. Kyoko K., Hiroyuki A., Hitomi O., Yasuyo M., Yoshifumi M., Susumu K. ; Retention and release behavior of insulin in Chitosan gel beads. ; J. Biomater Sci. Polymer Edn. Vol. 14, NO.11, pp.1243-1253(2003) 6. Yesim Sag* and Yücel Aktay ; A comparative study for the sorption of Cu(Ⅱ) ions by Chitin and Chitosan: Application of equilibrium and mass transfer models. ; Separation Sci. and Technology ,Vol. 37, NO.12, 2801-2822(2002) 7. Kazuo K., Shin-Jchi N., Michiaki M., Takayuki Y., Isao Furukawa ; Selective adsorption of metal ions on novel Chitosan supported sulfonic acid resin. ; J. of Chem. Engineering of Japan ,Vol. 30, NO. 5, 846-857(1997) 8. Rodney Boyer ; Concepts in Biochemistry(second edition) ; Published by John Wiley ＆ Sons 9. An-Chong C., Shing-shing S., Yu-Chuang L., Fwu-Long M. ; Enzymatic grafting of carboxyl groups on to Chitosan－to conferon Chitosan the property of a cationic dye adsorbent. ; Bioresource Technology, Vol. 91,157-162(2004) 10. Rudolph A. Abramovitch, Lu C., Evan Hicks, Joseph S. ; In situ remediation of soils contaminated with toxic metal ions using micro- wave energy. ; Chemosphere ,Vol.53, 1077-1085(2003) 11. 楊振昌，陳淑炫；常見除草劑巴拉刈與年年春中毒的處理；毒藥物季刊，第24 期，第1 頁(1997)。費雯绮，王喻其；植物保護手冊，第 834 頁 (2004) 12. Yu Qin, Cairans Andrew, Powies Stephen ; Glyphosate,