CO近红外高分辨吸收光谱特性的实验研究.PDFVIP

激光与光电子学进展 52, 113004(2015) Laser Optoelectronics Progress ©2015《中国激光》杂志社 CO近红外高分辨吸收光谱特性的实验研究 1 1 1 1 2 2 王尹秀 陈 东 贾兆丽 刘丽丽 高彦伟 张玉钧 1合肥工业大学仪器科学与光电工程学院,安徽 合肥 230009 2 中国科学院安徽光学精密机械研究所,安徽 合肥 230031 摘要 作为重要的大气污染物，CO气体浓度的变化是衡量大气污染状况的重要指标。针对大气污染组分CO高灵敏 红外光谱测量需要，研究了高分辨红外光谱特性参数精确测定方法，采用室温工作、窄线宽分布反馈式(DFB)半导体 激光器作为检测光源，精确测量了CO气体在1.56 μm附近的高分辨吸收光谱，利用Voigt线形模型对吸收谱线进行 拟合，获取了CO分子各吸收线的中心波长、谱线强度、压力自加宽系数等参量，并与理论结果进行了比较。 关键词 激光光学;近红外光谱;线宽;线强 中图分类号 O433.51 文献标识码 A doi: 10.3788/LOP52.113004 ExperimentalStudyontheCharacteristicsofNear-InfraredHigh ResolutionAbsorptionSpectroscopyofCO 1 1 1 1 2 2 WangYinxiu ChenDong JiaZhaoli LiuLili GaoYanwei ZhangYujun 1SchoolofInstrumentScienceandOpto-ElectronicEngineering,HefeiUniversityofTechnology, Hefei,Anhui 230009,China 2AnhuiInstituteofOpticsandFineMechanics,ChineseAcademyofSciences,Hefei,Anhui 230031,China Abstract Asoneofthemainairpollutants,theconcentrationchangeofcarbonmonoxideistheimportantindicator ofairquality.FortheneedofhighsensitiveinfraredspectroscopydetectiononCO,whichisoneofthemostimportant atmosphericpollutioncomponents,thecharacteristicsofhighresolutionabsorptionspectroscopydetectionmethod arestudied,andthehighresolutionabsorptionspectraofCOnear 1.56 μmarerecordedaccuratelybyusinga distributedfeed-back(DFB)diodelaser,whichhasnarrowlinewidthandworksatroomtemperatureaslightsource. TheVoigtprofilemodelisusedforabsorptionspectrallinesfitting,andthecenterwavelengths,lineintensitiesand self-broadeningcoefficientsofCOlinesarepreciselymea