课件：【】X射线荧光光谱仪基本原理及应用.pptVIP

技术指标及性能特点：4GN铑靶、超尖端、超薄窗(75um)、端窗X射线管，固态3.6kW高功率发生器，? 最大电压60kV，或最大电流120mA，9位晶体转换器，闪烁计数器， 最大线性计数1500kcps，流气正比计数器，最大线性计数2000kcps，流气正比计数器窗膜0.9um。 主要用途及使用方向：配备Uniquant 5.12版无标样分析软件。可对大部分固体样品中的70几个元素进行无标样半定量分析，特别适合基体复杂、无标准物质的样品分析。也可用于金属材料、高纯金属、化工产品、化学试剂、岩石、矿物、土壤、植物等样品中常量和痕量的定量分析。检出限：10μg/g左右，精密度小于1%。 3.4.2 生产厂家：荷兰PANalytical公司 3.4.3 生产厂家：英国牛津仪器公司 3.4.4 生产厂家：德国斯派克分析仪器公司 4 案例分析之一 Optimization of a glancing angle for simultaneous trace elemental analysis by using a portable total reflection X-ray fluorescence spectrometer Shinsuke Kunimura, Daisuke Watanabe, Jun Kawai Department of Materials Science and Engineering, Kyoto University, Sakyo-ku, Kyoto, 606-8501, Japan Spectrochimica Acta Part B 64 (2009) 288–290 The total reflection X-ray fluorescence (TXRF) analysis is a spectrometric method for trace elemental analysis. By using total reflection of incident X-rays on a sample holder with a specular surface, the intensities of the spectral background due to scattered X-rays are decreased. Therefore, highly sensitive analysis is performed by the TXRF analysis. Iida et al. reported that using monochromatic X-rays is more effective for improving sensitivity to trace elements than using non-monochromatic X-rays. Since then, monochromatic X-rays have been often used for trace elemental analysis in the TXRF analysis. Detection limits down to femtograms (10?15 g) are obtained by using a monochromatic synchrotron radiation. On the other hand, we have developed a portable TXRF spectrometer using continuum X-rays from a 1WX-ray tube, and a detection limit of 1 ng for Cr was achieved. Trace elements in leaching test solutions of soils and drinking water were detected by using the portable spectrometer. The X-rays with continuous energy distribution are used as the excitation source, and the reflectivity of the incident X-rays on a sample holder at a glancing angle varies according to the X-ray energies. Therefore, the signal to background ratios of each fluorescent X-r