冷轧变形对镀镍钢带腐蚀性能的影响.doc

冷轧变形对镀镍钢带腐蚀性能的影响 冷轧变形对镀镍钢带腐蚀性能的影响 3 钱 峰1 ,2 , 潘 勇1 ,2 ,3 3 , 周益春1 ,2 ,3 1. 湘潭大学材料与光电物理学院 ,湖南 湘潭 411105 ; 2.湘潭大学低维材料及其应用技术教育部重点实验室 ,湖南 湘潭 411105 ; 3. 湖南利德材料科技股份有限公司 ,湖南 株洲 412000 [摘要 ] 研究了冷轧变形对镀镍钢带耐腐蚀性能的影响. 利用电化学方法表征镍镀层的腐蚀行为 ,金相显微镜观察表面 形貌 ,XRD 法确定不同轧制变形量镍镀层中的残余应力. 结果表明 :2 %~4 %冷轧变形可以改进镀镍钢带的腐蚀性能 ,而 变形量超过 4 %会降低其性能. 关 键 词 :冷轧 ;腐蚀行为 ;镀镍钢带 ;电池钢壳 中图分类号 : TB304 文献标识码 :A 文章编号 :1000 - 5900 2007 03 - 0057 - 03 Effect of Cold Roll ing Deformation on the Corrosion Resistance of Electrodeposited Nickel - Coating/ Steel - Sheet Q IA N Feng1 ,2 , PA N Yong1 ,2 ,3 3 , Z HOU Yi - chun1 ,2 ,3 1. Faculty of Materials Optoelect ronics Physics , Xiangtan University ,Xiangtan 411105 China ; 2. Key Laboratory of Low Dimensional Materials and Application Technology , Ministry of Education , Xiangtan University , Xiangtan 411105 China ; 3. Hunan Leed Material Science Technology Limited Company , Zhuzhou , Hunan 412000 China 【Abstract】 The effect of cold rolled deformation on corrosion resistance property of electrodeposited nickel - coat2 ing/ steel - sheet ENS has been studied. The corrosion behaviors of nickel coating were investigated by electro2 chemical measurements and the morphology was studied by metallographic microscope. X - ray diffraction tech2 nique has been employed to determine the residual stress of nickel coating with different rolling deformations. It in2 dicated that the cold deformation with 2 %~4 % was found to improve the corrosion restsfance property of coating while the properties of corrosion resistance would reduce with the deformation beyond 4 %. Key words : cold rolling ; corrosion behavior ; electrodeposited nickel - coating/ steel - sheet ; steel battery shell 碱锰电池钢壳需要具有一定的抗氧化和腐蚀能力 ,通常采用镀镍方法保护钢壳 ,现行镀镍方法有两 种 ,一种是由钢带拉伸成壳后镀镍 ;另一种是钢带镀镍后拉伸制壳 预镀镍钢带 ,后一种生产效率高 ,品 质均一 ,制成的电池储存性能好[1 ]预镀镍钢带的生产工艺是 :在电池专用钢带上电沉积一层 3~4μm 的金属镍 - 扩散热处理 - 冷轧变形. 另外预镀镍钢带在加工成电池钢壳时 ,要经过 10 多次变形和深冲. 因此 ,研究镀镍钢带在扩散热处理后 ,冷轧变形对其抗腐蚀性能的影响规律 ,对制备优良的预镀镍钢带 具有一