第2章-聚合物燃烧和成炭.pptVIP

北京理工大学 2.8 烟的形成及抑制 (a) (b) (c) (d) The Bell reports consider two possibilities for trans-polyene formation. One is the straightforward Lewis acid isomerization of cis-alkenes（顺式烯烃） into trans-alkenes. The other has the MoO3 acting as a Lewis acid which interacts with chain chlorines and induces dehydrochlorination. 北京理工大学 2.8 烟的形成及抑制 (b) Reductive Coupling Mechanism The BF Goodrich Research Development Center Lattimer and Kroenke propose that transition metal smoke retarders, such as MoO3, promote early cross-linking of the PVC chains during thermal degradation. In effect, the smoke