二维层状金属硫化物ms2m=mos的n的制备及其电化学储锂性能的研究.docxVIP

IJ 万方数据 ABSTRACTAt ABSTRACT At present，there is increasing demand for high capacity lithium ion battery．Thus，it is critical to develop novel anode materials with high capacity,high charge-discharge efficiency and high cycle stability．Recent years，some metal sulfides Ms2(M=Mo，W：Sn，etc．)with layered structure have attracted extensive research interest for the lithiation／delithiation platform．As of the lithium-ion battery anode materials，the biggest advantage of layer metal sulfide is that it provide good diffusion channel for lithium ions，and effectively alleviate volumetric expansion during the charge and discharge progress， which exhibits superb cycle behavior and improved rate performance．Here，we mainly study liquid synthesis of the layered metal sulfide MS2(M=Mo，Sn)and its electrochemical performance．Main results of researches shown below． (1)Hollow fullerene-like MoS2(IF·MoS2)nanocages with diameter about 1 00 am were synthesized by novel and simple phase reduction method．IF—MoS2 exhibits excellent reversible capacity high 1 008 mAh／g，good cycle performance after 1 00 cycles and remained good cycling stability，when the current density is 1 000 mA／g (2)A simple method was used to synthesize precursor with(NH4)2MoS4 and CrAB．After heating at 800 oC for 2 hours with the protection of nitrogen，the single—layer MoS2／C composite was obtained． During the initial cycle，the reversible capacity of single．1ayer MoS2／C could reach 1403．7 mAh g～．After 1 00 cycles，a high capacity was still remained． (3)A series of tin based material(Sn，Sn02，SnS2)with nitrogen doped graphene were prepared via hydrothermal process．Among of the three materials，SnS2／NG exhibited the best electrochemical performance．After 1 00 cycles．the capacity retention rate SnS2／NG electrode could reach 84．2％ Key Words：metal sulfide，MoS2，Sns2，nitrogen doped grapherie Ill 万方数据 IV 万方数据 目录摘要 目录 摘要 l ABSTRACT ．．III 第一章绪论 ．．1 1．1锂离子电池概述 ．．2 】．2锂离子电池正极材料 ．．2 1．3锂离子电池负极材料 ．．3 1．3．1碳负极材料 3 1．3．2非碳负极材料 5 1．4本